Photocatalytic degradation of polyhydroxybutyrate films using titanium dioxide nanoparticles as a photocatalyst
- Authors: Hussain Z.1, El-Hiti G.A.2, Ahmed A.3, Altaee N.4, Yousif E.1
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Affiliations:
- Department of Chemistry, College of Science
- Cornea Research Chair, Department of Optometry, College of Applied Medical Sciences
- Polymer Research Unit, College of Science
- Department of Horticulture and Garden Engineering, College of Agriculture
- Issue: Vol 89, No 9 (2016)
- Pages: 1536-1543
- Section: Various Technological Processes
- URL: https://journals.rcsi.science/1070-4272/article/view/214315
- DOI: https://doi.org/10.1134/S1070427216090238
- ID: 214315
Cite item
Abstract
Photocatalytic degradation of polyhydroxybutyrate (PHB) polymeric films (30 μm thickness) containing different concentrations of titanium dioxide (TiO2) nanoparticles under ultraviolet (UV) irradiation (λmax = 313 nm) has been studied. The activity of TiO2 (0.001-0.005%) as a photocatalyst was determined by monitoring various functional group indices, weight loss in polymeric films and photodegradation rate constant (kd) with irradiation time. Photodegradation was found to be highly dependent on the TiO2 nanoparticles concentration and the UV irradiation time. The rate of PHB sample photodegradation was highest when the concentration of TiO2 was 0.005% (by weight) and lowest when its concentration was 0.001%.
About the authors
Zainab Hussain
Department of Chemistry, College of Science
Email: gelhiti@ksu.edu.sa
Iraq, Misan, 62001
Gamal A. El-Hiti
Cornea Research Chair, Department of Optometry, College of Applied Medical Sciences
Author for correspondence.
Email: gelhiti@ksu.edu.sa
Saudi Arabia, Riyadh, 11433
Ahmed Ahmed
Polymer Research Unit, College of Science
Email: gelhiti@ksu.edu.sa
Iraq, Bagdad
Nadia Altaee
Department of Horticulture and Garden Engineering, College of Agriculture
Email: gelhiti@ksu.edu.sa
Iraq, Babil, 51002
Emad Yousif
Department of Chemistry, College of Science
Email: gelhiti@ksu.edu.sa
Iraq, Baghdad, 64021
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