Photocatalytic degradation of polyhydroxybutyrate films using titanium dioxide nanoparticles as a photocatalyst


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Abstract

Photocatalytic degradation of polyhydroxybutyrate (PHB) polymeric films (30 μm thickness) containing different concentrations of titanium dioxide (TiO2) nanoparticles under ultraviolet (UV) irradiation (λmax = 313 nm) has been studied. The activity of TiO2 (0.001-0.005%) as a photocatalyst was determined by monitoring various functional group indices, weight loss in polymeric films and photodegradation rate constant (kd) with irradiation time. Photodegradation was found to be highly dependent on the TiO2 nanoparticles concentration and the UV irradiation time. The rate of PHB sample photodegradation was highest when the concentration of TiO2 was 0.005% (by weight) and lowest when its concentration was 0.001%.

About the authors

Zainab Hussain

Department of Chemistry, College of Science

Email: gelhiti@ksu.edu.sa
Iraq, Misan, 62001

Gamal A. El-Hiti

Cornea Research Chair, Department of Optometry, College of Applied Medical Sciences

Author for correspondence.
Email: gelhiti@ksu.edu.sa
Saudi Arabia, Riyadh, 11433

Ahmed Ahmed

Polymer Research Unit, College of Science

Email: gelhiti@ksu.edu.sa
Iraq, Bagdad

Nadia Altaee

Department of Horticulture and Garden Engineering, College of Agriculture

Email: gelhiti@ksu.edu.sa
Iraq, Babil, 51002

Emad Yousif

Department of Chemistry, College of Science

Email: gelhiti@ksu.edu.sa
Iraq, Baghdad, 64021

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