A Solution-Solid Phase Equilibrium in Ternary Systems Containing d-Elements Salts and Mixed Oxygen-Donor Solvent
- Authors: Bogachev N.A.1, Gorbunov A.O.1, Skripkin M.Y.1, Nikol’skii A.B.1
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Affiliations:
- St. Petersburg State University
- Issue: Vol 89, No 6 (2019)
- Pages: 1142-1153
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222934
- DOI: https://doi.org/10.1134/S1070363219060082
- ID: 222934
Cite item
Abstract
The results of the study of ternary systems containing copper, cobalt, nickel, and cadmium halides and sulfates in binary water-organic and mixed organic solvents are summarized. The influence of the donor-acceptor properties of the ternary system components, the relative dielectric permittivity, and the intermolecular association in the mixed solvent on the solubility of salts and the crystalline structure of solvates is analyzed.
About the authors
N. A. Bogachev
St. Petersburg State University
Author for correspondence.
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7-9, St. Petersburg, 199034
A. O. Gorbunov
St. Petersburg State University
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7-9, St. Petersburg, 199034
M. Yu. Skripkin
St. Petersburg State University
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7-9, St. Petersburg, 199034
A. B. Nikol’skii
St. Petersburg State University
Email: n.bogachev@spbu.ru
Russian Federation, Universitetskaya nab. 7-9, St. Petersburg, 199034