Replacement of Ligands in a Molecule of Polyhedral Phenylmetallosiloxane Containing Nickel and Sodium Ions


Дәйексөз келтіру

Толық мәтін

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Аннотация

The possibility of the partial or complete substitution of the outer-sphere solvate shell of n-butanol molecules by the nitrogen-containing compounds in the phenylnickelsodiumsiloxane complex. The high-symmetry spatially fixed rigidly cationic layer retains its structure. The obtained complexes Na2(μ-H2O)2(n-BuOH)2{[C6H5SiO2]6Ni4Na43-OH)2[C6H5SiO2]6} · 8(n-BuOH) · 2NH3 (II) and {[C6H5SiO2]6Ni4Na63-OH)2[C6H5SiO2]6} · 4(μ-C3H7NO) · 6(C3H7NO) · 2.8(H2O) · 0.6(C3H7NO) (III) are studied by X-ray diffraction analysis (CIF files CCDC nos. 1810736 (II) and 1810737 (III)).

Авторлар туралы

Yu. Vysochinskaya

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences

Email: olga@ineos.ac.ru
Ресей, Moscow, 119991; Moscow

P. Zhemchugov

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: olga@ineos.ac.ru
Ресей, Moscow, 119991

A. Anisimov

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: anisimov@ineos.ac.ru
Ресей, Moscow, 119991

F. Dolgushin

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: olga@ineos.ac.ru
Ресей, Moscow, 119991

O. Shchegolikhina

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: olga@ineos.ac.ru
Ресей, Moscow, 119991

A. Muzafarov

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences

Email: olga@ineos.ac.ru
Ресей, Moscow, 119991; Moscow

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