Crystal Structure of Mono- and Trinuclear Ni(II) Complexes with Bis-Azomethine Based on 2-Amino-3-Formylpyridine
- Авторы: Tupolova Y.P.1, Levchenkov S.I.1,2, Popov L.D.1, Posokhova S.V.3, Aleksandrov A.A.4
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Учреждения:
- Southern Federal University
- Southern Scientific Center, Russian Academy of Sciences
- Azov Black Sea Engineering Institute, Don State Agrarian University
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Выпуск: Том 45, № 3 (2019)
- Страницы: 208-214
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214663
- DOI: https://doi.org/10.1134/S107032841902009X
- ID: 214663
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Аннотация
The structure of a new mononuclear nickel(II) complex with bis-azomethine [Ni(H2L)]+ · CH3COO– · H2O, resulting from condensation of 1,3-diaminopropan-2-ol with 2-amino-3-formylpyridine (H3L), was studied by X-ray diffraction (CIF files CCDC nos. 1562927, 1562928). Apart from the mononuclear complex, the reaction gave a minor amount of the trinuclear metal chelate [Ni3L'(H2O)2]+ · (CH3COO)– · CH3OH · H2O, where L' is N5O2-donor ligand containing two 3-(((2-aminopyridin-2-yl)methylene)amino)-1-aminopropan-2-ol moieties linked by a 2-aminopyridine-3-methylene group.
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Об авторах
Yu. Tupolova
Southern Federal University
Автор, ответственный за переписку.
Email: yptupolova@sfedu.ru
Россия, Rostov-on-Don, 344006
S. Levchenkov
Southern Federal University; Southern Scientific Center, Russian Academy of Sciences
Email: yptupolova@sfedu.ru
Россия, Rostov-on-Don, 344006; Rostov-on-Don
L. Popov
Southern Federal University
Email: yptupolova@sfedu.ru
Россия, Rostov-on-Don, 344006
S. Posokhova
Azov Black Sea Engineering Institute, Don State Agrarian University
Email: yptupolova@sfedu.ru
Россия, Zernograd, Rostov oblast, 347740
A. Aleksandrov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: yptupolova@sfedu.ru
Россия, Moscow, 119991
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