Synthesis, structure, and fungicidal activity of mono- and binuclear mixed-ligand copper complex with p-nitrobenzoic acid and monoethanolamine


Дәйексөз келтіру

Толық мәтін

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Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

Mixed-ligand metal complexes based on ethanolamines and simple monosubstituted benzoic acids, in particular, mono- and binuclear copper complexes with monoethanolamine (MEA) and p-nitrobenzoic acid (PNBA), [Cu2+((PNBA)2-(MEA)2)] (I) and [2Cu2+((PNBA)4-(MEA)2(H2O)2)] (II), were prepared for the first time. The structures of the complexes were characterized by FT IR spectroscopy and X-ray diffraction (CIF files CCDC no. 1497849 (I) and no. 1497848 (II)). The doubly charged copper ions are coordinated at the vertices of octahedra, which are highly distorted due to the Jahn–Teller effect. In the crystals of the mononuclear complex I, the molecules are joined into columns, whereas in the binuclear compound II, a three-dimensional framework is formed owing to intermolecular H-bonds involving the nitro group. Fungicidal activities were found for compounds I, II, MEA, PNBA, previously obtained single-ligand copper complexes with MEA and PNBA, and MEA- and PNBA-based organic salt. The biological activity gradually increases in the series: ligand, single-ligand metal complex, organic salt, mono- and binuclear mixed-ligand complex, i.e., some ligands and copper ions show a synergistic effect.

Авторлар туралы

A. Ibragimov

Institute of General and Inorganic Chemistry

Хат алмасуға жауапты Автор.
Email: aziz_ibragimov@mail.ru
Өзбекстан, Tashkent, 100071

Zh. Ashurov

Sadikov Institute of Bioorganic Chemistry

Email: aziz_ibragimov@mail.ru
Өзбекстан, Tashkent, 100143

A. Ibragimov

Sadikov Institute of Bioorganic Chemistry

Email: aziz_ibragimov@mail.ru
Өзбекстан, Tashkent, 100143

Zh. Tashpulatov

Institute of Microbiology

Email: aziz_ibragimov@mail.ru
Өзбекстан, Tashkent, 100128

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