Synthesis and Crystal Structure of a Dioxomolybdenum(VI) Complex Derived from 2-Bromo-N'-(3,5-dichloro-2-hydroxybenzylidene)benzohydrazide with Catalytic Epoxidation Property


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Resumo

A dioxomolybdenum(VI) complex [MoO2L(EtOH)] (I), derived from the hydrazone ligand 2‑bromo-N'-(3,5-dichloro-2-hydroxybenzylidene)benzohydrazide has been prepared and characterized by physico-chemical and spectroscopic methods, as well as single crystal X-ray diffraction (CIF file CCDC no. 1840671). The hydrazone ligand coordinates to the Mo atom through the phenolate oxygen, imino nitrogen, and enolic oxygen. The Mo atom is six-coordinate in an octahedral geometry. Complex I shows high catalytic activity and selectivity in the epoxidation of cyclohexene with tert-butylhydroperoxide as primary oxidant.

Sobre autores

Y. Zhou

National Local Joint Enginering Laboratory for Advanced Textile Processing and Clean Production, Wuhan Textile University; School of Chemistry, Huazhong Normal University

Email: cuiym981248@163.com
República Popular da China, Wuhan, 430073; Wuhan, 430079

W. Liu

China Meheco Liyi Pharm Sci and Tech Co., Ltd.

Email: cuiym981248@163.com
República Popular da China, Wuhan, 430073

R. Lu

National Local Joint Enginering Laboratory for Advanced Textile Processing and Clean Production, Wuhan Textile University

Email: cuiym981248@163.com
República Popular da China, Wuhan, 430073

Y. Jin

National Local Joint Enginering Laboratory for Advanced Textile Processing and Clean Production, Wuhan Textile University

Email: cuiym981248@163.com
República Popular da China, Wuhan, 430073

M. Yang

National Local Joint Enginering Laboratory for Advanced Textile Processing and Clean Production, Wuhan Textile University

Email: cuiym981248@163.com
República Popular da China, Wuhan, 430073

Wu Chen

National Local Joint Enginering Laboratory for Advanced Textile Processing and Clean Production, Wuhan Textile University

Email: cuiym981248@163.com
República Popular da China, Wuhan, 430073

Y. Cui

National Local Joint Enginering Laboratory for Advanced Textile Processing and Clean Production, Wuhan Textile University; School of Environmental Engineering, Wuhan Textile University

Autor responsável pela correspondência
Email: cuiym981248@163.com
República Popular da China, Wuhan, 430073; Wuhan, 430073

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