Synthesis and Crystal Structure of a Dioxomolybdenum(VI) Complex Derived from 2-Bromo-N'-(3,5-dichloro-2-hydroxybenzylidene)benzohydrazide with Catalytic Epoxidation Property
- Autores: Zhou Y.Q.1,2, Liu W.T.3, Lu R.D.1, Jin Y.B.1, Yang M.D.1, Chen W.1, Cui Y.M.1,4
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Afiliações:
- National Local Joint Enginering Laboratory for Advanced Textile Processing and Clean Production, Wuhan Textile University
- School of Chemistry, Huazhong Normal University
- China Meheco Liyi Pharm Sci and Tech Co., Ltd.
- School of Environmental Engineering, Wuhan Textile University
- Edição: Volume 45, Nº 6 (2019)
- Páginas: 467-471
- Seção: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214755
- DOI: https://doi.org/10.1134/S1070328419060101
- ID: 214755
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Resumo
A dioxomolybdenum(VI) complex [MoO2L(EtOH)] (I), derived from the hydrazone ligand 2‑bromo-N'-(3,5-dichloro-2-hydroxybenzylidene)benzohydrazide has been prepared and characterized by physico-chemical and spectroscopic methods, as well as single crystal X-ray diffraction (CIF file CCDC no. 1840671). The hydrazone ligand coordinates to the Mo atom through the phenolate oxygen, imino nitrogen, and enolic oxygen. The Mo atom is six-coordinate in an octahedral geometry. Complex I shows high catalytic activity and selectivity in the epoxidation of cyclohexene with tert-butylhydroperoxide as primary oxidant.
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Sobre autores
Y. Zhou
National Local Joint Enginering Laboratory for Advanced Textile Processing and Clean Production, Wuhan Textile University; School of Chemistry, Huazhong Normal University
Email: cuiym981248@163.com
República Popular da China, Wuhan, 430073; Wuhan, 430079
W. Liu
China Meheco Liyi Pharm Sci and Tech Co., Ltd.
Email: cuiym981248@163.com
República Popular da China, Wuhan, 430073
R. Lu
National Local Joint Enginering Laboratory for Advanced Textile Processing and Clean Production, Wuhan Textile University
Email: cuiym981248@163.com
República Popular da China, Wuhan, 430073
Y. Jin
National Local Joint Enginering Laboratory for Advanced Textile Processing and Clean Production, Wuhan Textile University
Email: cuiym981248@163.com
República Popular da China, Wuhan, 430073
M. Yang
National Local Joint Enginering Laboratory for Advanced Textile Processing and Clean Production, Wuhan Textile University
Email: cuiym981248@163.com
República Popular da China, Wuhan, 430073
Wu Chen
National Local Joint Enginering Laboratory for Advanced Textile Processing and Clean Production, Wuhan Textile University
Email: cuiym981248@163.com
República Popular da China, Wuhan, 430073
Y. Cui
National Local Joint Enginering Laboratory for Advanced Textile Processing and Clean Production, Wuhan Textile University; School of Environmental Engineering, Wuhan Textile University
Autor responsável pela correspondência
Email: cuiym981248@163.com
República Popular da China, Wuhan, 430073; Wuhan, 430073
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