Reactivity of Two 16e Half-Sandwich Cobalt Complexes Containing 1,2-Dicarba-closo-Dodecaborane-1,2-Dichalcogenolate (E2C2B10H10)2– (E = S, Se) Units toward Triphenylphosphine
- 作者: Ye H.D.1, Zhan Y.L.1, Liang J.1, Ye T.Y.1, Zhang D.1, Peng H.N.1, Hu J.R.1
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隶属关系:
- Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, Jiangxi Provincial Research of Targeting Pharmaceutical Engineering Technology
- 期: 卷 44, 编号 7 (2018)
- 页面: 454-459
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214570
- DOI: https://doi.org/10.1134/S1070328418070047
- ID: 214570
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详细
Treatment of o-carborane, n-butyllithium, sulfur (or selenium) and MeCpCo(CO)I2 (or Cp*Co(CO)I2) (Cp* = pentamethylcyclopentadienyl) under argon leads to half-sandwich carborane complex MeCpCo(S2C2B10H10) (I) (or Cp*Co(Se2C2B10H10) (II)). Complex I reacts with triphenylphosphine to afford addition product MeCpCo(S2C2B10H10)(PPh3) (III). However, II does not react with triphenylphosphine. Complexes II and III have been characterized by elemental analysis, mass, NMR spectroscopy, IR and X-ray structural analyses (CIF files CCDC nos. 1571705 (II) and 1571706 (III)).
作者简介
H. Ye
Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, Jiangxi Provincial Research of Targeting Pharmaceutical Engineering Technology
编辑信件的主要联系方式.
Email: yehongde@163.com
中国, Jiangxi, 334001
Y. Zhan
Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, Jiangxi Provincial Research of Targeting Pharmaceutical Engineering Technology
Email: yehongde@163.com
中国, Jiangxi, 334001
J. Liang
Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, Jiangxi Provincial Research of Targeting Pharmaceutical Engineering Technology
Email: yehongde@163.com
中国, Jiangxi, 334001
T. Ye
Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, Jiangxi Provincial Research of Targeting Pharmaceutical Engineering Technology
Email: yehongde@163.com
中国, Jiangxi, 334001
D. Zhang
Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, Jiangxi Provincial Research of Targeting Pharmaceutical Engineering Technology
Email: yehongde@163.com
中国, Jiangxi, 334001
H. Peng
Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, Jiangxi Provincial Research of Targeting Pharmaceutical Engineering Technology
Email: yehongde@163.com
中国, Jiangxi, 334001
J. Hu
Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, Jiangxi Provincial Research of Targeting Pharmaceutical Engineering Technology
Email: yehongde@163.com
中国, Jiangxi, 334001
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