Reactivity of Two 16e Half-Sandwich Cobalt Complexes Containing 1,2-Dicarba-closo-Dodecaborane-1,2-Dichalcogenolate (E2C2B10H10)2– (E = S, Se) Units toward Triphenylphosphine


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Treatment of o-carborane, n-butyllithium, sulfur (or selenium) and MeCpCo(CO)I2 (or Cp*Co(CO)I2) (Cp* = pentamethylcyclopentadienyl) under argon leads to half-sandwich carborane complex MeCpCo(S2C2B10H10) (I) (or Cp*Co(Se2C2B10H10) (II)). Complex I reacts with triphenylphosphine to afford addition product MeCpCo(S2C2B10H10)(PPh3) (III). However, II does not react with triphenylphosphine. Complexes II and III have been characterized by elemental analysis, mass, NMR spectroscopy, IR and X-ray structural analyses (CIF files CCDC nos. 1571705 (II) and 1571706 (III)).

作者简介

H. Ye

Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, Jiangxi Provincial Research of Targeting Pharmaceutical Engineering Technology

编辑信件的主要联系方式.
Email: yehongde@163.com
中国, Jiangxi, 334001

Y. Zhan

Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, Jiangxi Provincial Research of Targeting Pharmaceutical Engineering Technology

Email: yehongde@163.com
中国, Jiangxi, 334001

J. Liang

Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, Jiangxi Provincial Research of Targeting Pharmaceutical Engineering Technology

Email: yehongde@163.com
中国, Jiangxi, 334001

T. Ye

Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, Jiangxi Provincial Research of Targeting Pharmaceutical Engineering Technology

Email: yehongde@163.com
中国, Jiangxi, 334001

D. Zhang

Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, Jiangxi Provincial Research of Targeting Pharmaceutical Engineering Technology

Email: yehongde@163.com
中国, Jiangxi, 334001

H. Peng

Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, Jiangxi Provincial Research of Targeting Pharmaceutical Engineering Technology

Email: yehongde@163.com
中国, Jiangxi, 334001

J. Hu

Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, Jiangxi Provincial Research of Targeting Pharmaceutical Engineering Technology

Email: yehongde@163.com
中国, Jiangxi, 334001

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