1D-Bromobismuthates of Dipyridinoalkane Derivatives


Citar

Texto integral

Acesso aberto Acesso aberto
Acesso é fechado Acesso está concedido
Acesso é fechado Somente assinantes

Resumo

The following bromobismuthates of organic cations (dipyridinoalkane derivatives) are synthesized and characterized: (4-NH2PyC5)BiBr5 (I), (2-MePyC2)BiBr5 (II), (2-NH2PyC10)BiBr5 · 0.65H2O (III), (2-NH2PyC10)4H5O2(BiBr6)3 (IV), (2-NH2PyС6)2KBi2Br11 (V), (2-NH2PyC6)H3OBiBr6 · 2.33H2O (VI), and (2-NH2PyC6)3(BiBr6)2 · CH3CN (VII). Three compounds obtained (I–III) contain the zigzag 1D chain (BiBr5)n. A new type of 1D chains, (KBi2Br11)n, is found in the structure of compound V. Pseudo-1D chains of BiBr63− anions can be observed in the 3D structures of compounds IV, VI, and VII. The crystallographic data were deposited with the Cambridge Crystallographic Data Centre (CIF files CCDC 1569478 (I)–1569484 (VII), respectively).

Sobre autores

P. Buikin

Kurnakov Institute of General and Inorganic Chemistry; Mendeleev University of Chemical Technology

Autor responsável pela correspondência
Email: peterzzz@mail.ru
Rússia, Moscow, 119991; Moscow, 125190

A. Rudenko

Mendeleev University of Chemical Technology

Email: peterzzz@mail.ru
Rússia, Moscow, 125190

A. Baranchikov

Kurnakov Institute of General and Inorganic Chemistry

Email: peterzzz@mail.ru
Rússia, Moscow, 119991

A. Ilyukhin

Kurnakov Institute of General and Inorganic Chemistry

Email: peterzzz@mail.ru
Rússia, Moscow, 119991

V. Kotov

Kurnakov Institute of General and Inorganic Chemistry; Mendeleev University of Chemical Technology

Email: peterzzz@mail.ru
Rússia, Moscow, 119991; Moscow, 125190

Arquivos suplementares

Arquivos suplementares
Ação
1. JATS XML

Declaração de direitos autorais © Pleiades Publishing, Ltd., 2018