1D-Bromobismuthates of Dipyridinoalkane Derivatives
- Autores: Buikin P.A.1,2, Rudenko A.Y.2, Baranchikov A.E.1, Ilyukhin A.B.1, Kotov V.Y.1,2
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Afiliações:
- Kurnakov Institute of General and Inorganic Chemistry
- Mendeleev University of Chemical Technology
- Edição: Volume 44, Nº 6 (2018)
- Páginas: 373-379
- Seção: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214527
- DOI: https://doi.org/10.1134/S1070328418060015
- ID: 214527
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Resumo
The following bromobismuthates of organic cations (dipyridinoalkane derivatives) are synthesized and characterized: (4-NH2PyC5)BiBr5 (I), (2-MePyC2)BiBr5 (II), (2-NH2PyC10)BiBr5 · 0.65H2O (III), (2-NH2PyC10)4H5O2(BiBr6)3 (IV), (2-NH2PyС6)2KBi2Br11 (V), (2-NH2PyC6)H3OBiBr6 · 2.33H2O (VI), and (2-NH2PyC6)3(BiBr6)2 · CH3CN (VII). Three compounds obtained (I–III) contain the zigzag 1D chain (BiBr5)n. A new type of 1D chains, (KBi2Br11)n, is found in the structure of compound V. Pseudo-1D chains of BiBr63− anions can be observed in the 3D structures of compounds IV, VI, and VII. The crystallographic data were deposited with the Cambridge Crystallographic Data Centre (CIF files CCDC 1569478 (I)–1569484 (VII), respectively).
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Sobre autores
P. Buikin
Kurnakov Institute of General and Inorganic Chemistry; Mendeleev University of Chemical Technology
Autor responsável pela correspondência
Email: peterzzz@mail.ru
Rússia, Moscow, 119991; Moscow, 125190
A. Rudenko
Mendeleev University of Chemical Technology
Email: peterzzz@mail.ru
Rússia, Moscow, 125190
A. Baranchikov
Kurnakov Institute of General and Inorganic Chemistry
Email: peterzzz@mail.ru
Rússia, Moscow, 119991
A. Ilyukhin
Kurnakov Institute of General and Inorganic Chemistry
Email: peterzzz@mail.ru
Rússia, Moscow, 119991
V. Kotov
Kurnakov Institute of General and Inorganic Chemistry; Mendeleev University of Chemical Technology
Email: peterzzz@mail.ru
Rússia, Moscow, 119991; Moscow, 125190
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