Synthesis, Structure, and Fluorescence of a Novel Samarium Compound
- Авторлар: Fang X.N.1, Tang B.X.1, Yi X.G.1, Kuang R.Y.1, Xu Y.P.1
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Мекемелер:
- School of Chemistry and Chemical Engineering
- Шығарылым: Том 44, № 3 (2018)
- Беттер: 169-172
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214415
- DOI: https://doi.org/10.1134/S1070328418030016
- ID: 214415
Дәйексөз келтіру
Аннотация
A novel samarium compound, [Sm(Phen)2(H2O)5]2(Phen)2(Bipy)Cl6 · 7H2O (I) (Phen = 1,10-phenanthroline and Bipy = 2,2'-bipyridine), was prepared by a solvothermal reaction. The crystal structure of I was characterized by X-ray single-crystal diffraction method (CIF file CCDC no. 1025736). Compound I is an isolated structure with the samarium ions possessing a nine-coordinated distorted monocapped square antiprism geometry. There are abundant hydrogen bonding and π–π stacking interactions which connect the molecules together to yield a three-dimensional (3D) supramolecular structure. The fluorescence spectra data reveals that I can display the characteristic emission 4G5/2 → 6HJ transitions (J = 5/2, 7/2, 9/2 and 11/2, respectively) of Sm3+ ions.
Негізгі сөздер
Авторлар туралы
X. Fang
School of Chemistry and Chemical Engineering
Хат алмасуға жауапты Автор.
Email: fangxiaoniu@163.com
ҚХР, Ji’an, Jiangxi, 343009
B. Tang
School of Chemistry and Chemical Engineering
Email: fangxiaoniu@163.com
ҚХР, Ji’an, Jiangxi, 343009
X. Yi
School of Chemistry and Chemical Engineering
Email: fangxiaoniu@163.com
ҚХР, Ji’an, Jiangxi, 343009
R. Kuang
School of Chemistry and Chemical Engineering
Email: fangxiaoniu@163.com
ҚХР, Ji’an, Jiangxi, 343009
Y. Xu
School of Chemistry and Chemical Engineering
Email: fangxiaoniu@163.com
ҚХР, Ji’an, Jiangxi, 343009
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