Two Novel Supramolecules Built by Dimethylphenyl Imidazole Dicarboxylate: Syntheses, Structures, and Thermal Properties
- Autores: Lin X.S.1, Sang Y.L.1
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Afiliações:
- College of Chemistry and Chemical Engineering, Chifeng University
- Edição: Volume 44, Nº 9 (2018)
- Páginas: 533-539
- Seção: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214060
- DOI: https://doi.org/10.1134/S1070328418090051
- ID: 214060
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Resumo
By solvothermal reactions of ZnSO4 ⋅ 7H2O and NiSO4 ⋅ 6H2O with 2-(3,4-dimethylphenyl)-1H-imidazole-4,5-dicarboxylic acid (3,4-DMPhH3IDC), respectively, two supramolecular complexes, [Zn(3,4-DMPhHIDC)2(H2O)2]n (I) and [Ni(3,4-DMPhHIDC)2(H2O)2]n (II) have been successfully prepared and structurally characterized by single-crystal X-ray diffraction (CIF files CCDC nos. 1440305 (I) and 1440316 (II)), elemental analyses, and IR spectroscopy. The results show that ligand 3,4-DMPhH3IDC in the two complexes has quite strong coordination ability, and the 3D solid-state supramolecular structures of I and II involve intermolecular hydrogen bonds. The thermal properties of the complexes have also been investigated and discussed.
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Sobre autores
X. Lin
College of Chemistry and Chemical Engineering, Chifeng University
Email: sangyali0814@126.com
República Popular da China, ChifengNeimenggu, 024000
Y. Sang
College of Chemistry and Chemical Engineering, Chifeng University
Autor responsável pela correspondência
Email: sangyali0814@126.com
República Popular da China, ChifengNeimenggu, 024000
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