CpFe(CO)2TePh as a ligand for organometallic dihalides Fe(CO)4I2, (p-Cymene)RuI2, and Me5C5RhI2: Synthesis and molecular structures
- Авторы: Pasynskii A.A.1, Skabitskiy I.V.1, Torubaev Y.V.1, Pavlova A.V.1, Shapovalov S.S.1, Tikhonova O.G.2, Sakharov S.G.1
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Учреждения:
- Kurnakov Institute of General and Inorganic Chemistry
- Higher Chemical College of the Russian Academy of Sciences
- Выпуск: Том 43, № 1 (2017)
- Страницы: 44-49
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213723
- DOI: https://doi.org/10.1134/S1070328417010067
- ID: 213723
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Аннотация
CpFe(CO)2TePh (I) can substitute one carbonyl group in Fe(CO)4I2 providing Fe(CO)3I2(μ-TePh)Fe(CO)2Cp (II) or play role of ligand to monomeric fragments [(p-Cymene)RuI2] and [Сp*RhI2] (p-Cymene = (η6-1-isopropyl-4-methylbenzene); Сp* = η5-pentamethylcyclopentadienyl) provides the complexes (p-Cymene)RuI2(μ-TePh)Fe(CO)2Cp (III) and Cp*RhCl2(μ-TePh)Fe(CO)2Cp (IV), respectively. The single-crystal X-ray diffraction of complexes II–IV (CIF files CCDC nos. 1038124 (II), 1038127 (III), 1038125 (IV)) revealed the shortening of М–Те bonds and the presence of intramolecular I…Te contacts.
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Об авторах
A. Pasynskii
Kurnakov Institute of General and Inorganic Chemistry
Автор, ответственный за переписку.
Email: aapas@rambler.ru
Россия, Leninskii pr. 31, Moscow, 119991
I. Skabitskiy
Kurnakov Institute of General and Inorganic Chemistry
Email: aapas@rambler.ru
Россия, Leninskii pr. 31, Moscow, 119991
Yu. Torubaev
Kurnakov Institute of General and Inorganic Chemistry
Email: aapas@rambler.ru
Россия, Leninskii pr. 31, Moscow, 119991
A. Pavlova
Kurnakov Institute of General and Inorganic Chemistry
Email: aapas@rambler.ru
Россия, Leninskii pr. 31, Moscow, 119991
S. Shapovalov
Kurnakov Institute of General and Inorganic Chemistry
Email: aapas@rambler.ru
Россия, Leninskii pr. 31, Moscow, 119991
O. Tikhonova
Higher Chemical College of the Russian Academy of Sciences
Email: aapas@rambler.ru
Россия, Miusskaya pl. 9, Moscow, 125047
S. Sakharov
Kurnakov Institute of General and Inorganic Chemistry
Email: aapas@rambler.ru
Россия, Leninskii pr. 31, Moscow, 119991
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