Synthesis, crystal structures, and antimicrobial activity of copper(II) and zinc(II) complexes derived from 2-bromo-4-chloro-6-[(2-morpholin-4-ylethylimino)methyl]phenol
- Авторы: Hu X.M.1, Zhao G.Q.1, Xue L.W.1, Yang W.C.1
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Учреждения:
- College of Chemistry and Chemical Engineering
- Выпуск: Том 42, № 6 (2016)
- Страницы: 418-422
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213429
- DOI: https://doi.org/10.1134/S107032841605002X
- ID: 213429
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Аннотация
An end-to-end azido-bridged dinuclear copper(II) complex [Cu2L2(μ1,3-N3)](NO3) (I) and a mononuclear zinc(II) complex [ZnCl2(HL)] • CH3OH (II), where L is 2-brom-4-chloro-6-[(2-morpholin- 4-ylethylimino)methyl]phenolate, have been prepared and characterized by elemental analyses, IR, and single crystal X-ray crystallographic determination (CIF files CCDC nos. 1415217 (I), 1415218 for (II)). The crystal of I is monoclinic: space group C2/c, a = 28.684(2), b = 7.1787(5), c = 18.292(1) Å, β = 117.887(3)°, V = 3329.1(4) Å3, Z = 4. The crystal of II is monoclinic: space group P21/c, a = 10.8207(9), b = 12.3398(7), c = 14.9477(7) Å, β = 93.473(3)°, V = 1992.2(2) Å3, Z = 4. The Schiff base ligand in I coordinates to the Cu atom through the phenolate O, imine N, and morpholine N atoms, while the Schiff base ligand in II coordinates to the Zn atom through the phenolate O and imine N atoms, with the morpholine N atom protonated. The effect of these complexes on the antimicrobial activity against Staphylococcus aureus, Escherichia coli, and Candida albicans was studied.
Об авторах
X. Hu
College of Chemistry and Chemical Engineering
Email: pdsuchemistry@163.com
Китай, Pingdingshan Henan, 467000
G. Zhao
College of Chemistry and Chemical Engineering
Email: pdsuchemistry@163.com
Китай, Pingdingshan Henan, 467000
L. Xue
College of Chemistry and Chemical Engineering
Автор, ответственный за переписку.
Email: pdsuchemistry@163.com
Китай, Pingdingshan Henan, 467000
W. Yang
College of Chemistry and Chemical Engineering
Email: pdsuchemistry@163.com
Китай, Pingdingshan Henan, 467000
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