New Ni(II) and Co(II) coordination compounds construction from the ditopic 1,2,3-triazol-based aromatic heterocyclic polycarboxylic ligand
- Autores: Zhou Z.1, Zhang W.Q.1, Bian R.R.1, Lan C.X.1, Gu W.2,3, Liu X.2,3, Liao S.Y.1
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Afiliações:
- Department of Applied Chemistry
- Department of Chemistry
- Collaborative Innovation Center of Chemical Science and Engineering
- Edição: Volume 42, Nº 6 (2016)
- Páginas: 385-391
- Seção: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213422
- DOI: https://doi.org/10.1134/S1070328416060099
- ID: 213422
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Resumo
Mononuclear compound I ([Co(Ptia)2(H2O)4] • H2O) and 1D chain compound II ([Ni4(Cptia)4(H2O)12]∞) have been constructed from the new ditopic 1,2,3-trazol-based aromatic heterocyclic carboxylic ligand, 4-(4-carboxy-1H-1,2,3-triazol-1-yl) benzoic acid) (H2Cptia), under different pH conditions by using the hydrothermal method. Their structure was characterized by single crystal X-ray diffraction (СIF files CCDC nos. 1409531 (I) and 1409531 (II)), IR spectra, and elemental analysis. Compound I is a mononuclear compound. In II, two sets of parallel arrangement 1D chains orient in different directions. The results of their magnetic measurements display the antiferromagnetic interaction exists among the paramagnetic ions.
Sobre autores
Z. Zhou
Department of Applied Chemistry
Email: 18202587221@163.com
República Popular da China, Tianjin, 300384
W. Zhang
Department of Applied Chemistry
Email: 18202587221@163.com
República Popular da China, Tianjin, 300384
R. Bian
Department of Applied Chemistry
Email: 18202587221@163.com
República Popular da China, Tianjin, 300384
C. Lan
Department of Applied Chemistry
Email: 18202587221@163.com
República Popular da China, Tianjin, 300384
W. Gu
Department of Chemistry; Collaborative Innovation Center of Chemical Science and Engineering
Email: 18202587221@163.com
República Popular da China, Tianjin, 300071; Tianjin, 300071
X. Liu
Department of Chemistry; Collaborative Innovation Center of Chemical Science and Engineering
Autor responsável pela correspondência
Email: liuxin64@nankai.edu.cn
República Popular da China, Tianjin, 300071; Tianjin, 300071
S. Liao
Department of Applied Chemistry
Autor responsável pela correspondência
Email: 18202587221@163.com
República Popular da China, Tianjin, 300384
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