Email this article Na4[trans-{Cp*Rh}2Ta6O19] · 24H2O: Synthesis, structure, solution studies
- Authors: Abramov P.A.1,2, Kompankov N.B.1, Sokolov M.N.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry Siberian Branch
- Novosibirsk State University
- Issue: Vol 42, No 5 (2016)
- Pages: 311-315
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213402
- DOI: https://doi.org/10.1134/S1070328416050018
- ID: 213402
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Abstract
Reaction of [Cp*RhCl2]2 (Cp* = η5-C5(CH3)5) with Na8[Ta6O19] · 24.5H2O, taken in {Cp*Rh}2+/[Ta6O19]8– 2: 1 molar ratio, in water leads to a new noble-metal-POM complex Na4[trans-{Cp*Rh}2Ta6O19] · 24H2O (I), which was isolated and characterized by XRD (CIF file CCDC no. 1416810), elemental analysis, NMR and IR spectroscopy.
About the authors
P. A. Abramov
Nikolaev Institute of Inorganic Chemistry Siberian Branch; Novosibirsk State University
Author for correspondence.
Email: abramov@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
N. B. Kompankov
Nikolaev Institute of Inorganic Chemistry Siberian Branch
Email: abramov@niic.nsc.ru
Russian Federation, Novosibirsk
M. N. Sokolov
Nikolaev Institute of Inorganic Chemistry Siberian Branch; Novosibirsk State University
Email: abramov@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
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