Email this article Methyl Propiolate Cluster Complex (Ph4P)2[W6I8(C≡C–C(O)OCH3)6]
- Authors: Mikhailov M.A.1, Abramov P.A.1,2, Mironova A.D.1, Gallyamov M.R.1, Sheven’ D.G.1, Pervukhin V.V.1, Sokolov M.N.1,2,3
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
- Novosibirsk State University
- Kazan Federal University
- Issue: Vol 45, No 1 (2019)
- Pages: 56-61
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214599
- DOI: https://doi.org/10.1134/S1070328419010081
- ID: 214599
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Abstract
A new organometallic iodide cluster complex (Bu4N)2[W6I8(C≡C–C(O)OCH3)6] (I), analogous to the previously described (Bu4N)2[Mo6I8(C≡C–C(O)OCH3)6], was obtained by the reaction of (Bu4N)2[W6I14] with silver methyl propiolate AgC≡C–C(O)OCH3. The crystal structure was established for the tetraphenylphosphonium salt (Ph4P)2[W6I8(C≡C–C(O)OCH3)6] (II). According to X-ray diffraction (CIF file CCDC no. 1829205), tungsten atoms in II are coordinated by terminal carbon atoms of methyl propiolate ligands at W–C distances of 2.220(12)–2.268(14) Å. The methyl propiolate complexes were characterized by electrospray mass spectrometry, 1H and 13C NMR spectroscopy, elemental analysis, and IR spectroscopy.
About the authors
M. A. Mikhailov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Author for correspondence.
Email: mikhajlovmaks@yandex.ru
Russian Federation, Novosibirsk, 630090
P. A. Abramov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University
Email: mikhajlovmaks@yandex.ru
Russian Federation, Novosibirsk, 630090; Novosibirsk, 630090
A. D. Mironova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Email: mikhajlovmaks@yandex.ru
Russian Federation, Novosibirsk, 630090
M. R. Gallyamov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Email: mikhajlovmaks@yandex.ru
Russian Federation, Novosibirsk, 630090
D. G. Sheven’
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Email: mikhajlovmaks@yandex.ru
Russian Federation, Novosibirsk, 630090
V. V. Pervukhin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Email: mikhajlovmaks@yandex.ru
Russian Federation, Novosibirsk, 630090
M. N. Sokolov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University; Kazan Federal University
Email: mikhajlovmaks@yandex.ru
Russian Federation, Novosibirsk, 630090; Novosibirsk, 630090; Kazan, 420008
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