Nanostructured Platinum-Free Catalysts of Oxygen Reduction based on Metal Chalcogenide Cobalt Clusters


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Аннотация

Nanostructured catalysts were synthesized by deposition of cobalt selenide and telluride on highly dispersed carbon black from solutions of corresponding metal chalcogenide clusters. The catalysts were characterized by powder X-ray diffraction, energy dispersive X-ray spectroscopy, and scanning electron microscopy. The electroreduction of oxygen at these catalysts is accompanied by consumption of four electrons. The catalysts were shown to be tolerant to methanol.

Авторлар туралы

V. Grinberg

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: vitgreen@mail.ru
Ресей, Moscow, 199071

N. Mayorova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: vitgreen@mail.ru
Ресей, Moscow, 199071

A. Pasynskii

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: vitgreen@mail.ru
Ресей, Moscow, 119991

A. Modestov

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: vitgreen@mail.ru
Ресей, Moscow, 199071

A. Shiryaev

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: vitgreen@mail.ru
Ресей, Moscow, 199071

V. Vysotskii

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: vitgreen@mail.ru
Ресей, Moscow, 199071

A. Nogai

Gumilyov Eurasian National University

Email: vitgreen@mail.ru
Қазақстан, Astana, 010008

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