Email this article Synthesis and Crystal Structure of Binuclear Half-Sandwich Rhodium Carborane Complex
- Authors: Jia A.Q.1, Liu D.1, Fang D.W.1, Qian Z.1
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Affiliations:
- Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology
- Issue: Vol 44, No 9 (2018)
- Pages: 559-564
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214077
- DOI: https://doi.org/10.1134/S1070328418090038
- ID: 214077
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Abstract
Reaction of unsaturated 16e half-sandwich rhodium carborane complex [Cp*Rh(S2C2B10H10)] (Cp* = pentamethyl-cyclopentadienyl) with half equiv. (m-pyridyl)N=C(C10H6)C=N(m-pyridyl) (mPy-Bian, L) afforded a bi-nuclear complex [{Cp*Rh(S2C2B10H10)}2(μ-L)] (I), leaving α-diimine moiety of the L ligand as free coordination site. Compounds L and I have been characterized by single crystal X-ray diffraction (CIF files nos. 1586584 (L) and 1586585 (I)). Compound L crystallizes in the monoclinic space group C2/c with a = 21.51(3), b = 8.884(13), c = 9.414(14) Å, β = 112.540(19)°, and Z = 4. Complex I crystallizes in the orthorhombic space group Pnma with a = 15.741(2), b = 34.062(5), c = 14.960(2) Å, and Z = 4.
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About the authors
A. Q. Jia
Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology
Author for correspondence.
Email: jaiquan@ahut.edu.cn
China, Ma’anshanAnhui, 243002
D. Liu
Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology
Email: jaiquan@ahut.edu.cn
China, Ma’anshanAnhui, 243002
D. W. Fang
Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology
Email: jaiquan@ahut.edu.cn
China, Ma’anshanAnhui, 243002
Z. Qian
Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology
Email: jaiquan@ahut.edu.cn
China, Ma’anshanAnhui, 243002
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