Effect of the Nature of the Polymer Matrix on the Luminescence of Tb(III) Complexes with β-Diketone Copolymers

S. B. Meshkova; O. V. Shevchenko; V. Yu. Kovalenko; P. G. Doga; V. P. Gorodnyuk

doi:10.1134/S1070328418020070

Effect of the Nature of the Polymer Matrix on the Luminescence of Tb(III) Complexes with β-Diketone Copolymers

Authors: Meshkova S.B.¹, Shevchenko O.V.², Kovalenko V.Y.², Doga P.G.¹, Gorodnyuk V.P.¹
Affiliations:
1. Bogatsky Physicochemical Institute
2. Odessa Mechnikov National University
Issue: Vol 44, No 3 (2018)
Pages: 220-225
Section: Article
URL: https://journals.rcsi.science/1070-3284/article/view/214452
DOI: https://doi.org/10.1134/S1070328418020070
ID: 214452

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Abstract

The formation conditions and luminescence of Tb(III) complexes with synthesized copolymers of unsaturated acetylacetone derivatives with styrene and methyl methacrylate were studied. The luminescence intensity of these Tb(III) complexes was found to depend on the β-diketone substituent nature (CH₃, CF₃, C₆H₅) and structure (linear, branched) and the β-diketone to monomer ratio in the polymerizing mixture.