Email this article Formation of Polynuclear Cadmium Pivalates in Exchange Reactions
- Authors: Gogoleva N.V.1, Sidorov A.A.1, Nelyubina Y.V.1,2, Shmelev M.A.1, Aleksandrov G.G.1, Kuznetsova G.N.1, Kiskin M.A.1, Eremenko I.L.1,2
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Issue: Vol 44, No 8 (2018)
- Pages: 473-482
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214023
- DOI: https://doi.org/10.1134/S107032841808002X
- ID: 214023
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Abstract
The exchange reaction of CdCl2 ⋅ 2H2O with KPiv affords cadmium(II) trimethyl acetate complexes (K[Cd6(Piv)12Cl] ⋅ 2MeCN (I), [K2Cd3(Piv)8(H2O)6] (II), and [Cd(Piv)2(Н2О)2] (III) as a mixture with complex II and [K3Cd2(Piv)7(MeCN)2]n (IV) (HPiv is trimethylacetic acid). The exchange reaction of CdSO4 ⋅ 8/3H2O with Ba(Piv)2 makes it possible to obtain complex III in a quantitative yield. Complex III can also be isolated by the recrystallization of {Cd(Piv)2} from water. The recrystallization of complex III or {Cd(Piv)2} from MeCN affords hexanuclear complex [Cd6(Piv)12(MeCN)2] (V), which transforms into complex III upon recrystallization from water. All new compounds are characterized by the data of single-crystal X-ray diffraction analysis (CIF files CCDC no. 1572202–1572206), IR spectroscopy, and C,H,N analysis.
About the authors
N. V. Gogoleva
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: mkiskin@igic.ras.ru
Russian Federation, Moscow, 119991
A. A. Sidorov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: mkiskin@igic.ras.ru
Russian Federation, Moscow, 119991
Yu. V. Nelyubina
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: mkiskin@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 119991
M. A. Shmelev
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: mkiskin@igic.ras.ru
Russian Federation, Moscow, 119991
G. G. Aleksandrov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: mkiskin@igic.ras.ru
Russian Federation, Moscow, 119991
G. N. Kuznetsova
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: mkiskin@igic.ras.ru
Russian Federation, Moscow, 119991
M. A. Kiskin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: mkiskin@igic.ras.ru
Russian Federation, Moscow, 119991
I. L. Eremenko
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: mkiskin@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 119991
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