Coordination polymers of rare-earth elements with 2-aminoterephthalic acid


Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

Coordination polymers of REEs with 2-aminoterephthalic acid [Ln2(C8H5NO4)3(H2O)5]n · 2nH2O (Ln = Eu, Gd, or Tb) and [Y2(C8H5NO4)3(H2O)4]n · 4nH2O were prepared by hydrothermal synthesis. Studies of the thermal behavior of these coordination polymers have shown that the removal of the solvate and the coordinated water molecules occurs at heating to 250°C and dehydratation products are stable up to 400°C. Detailed studies of the magnetic behavior of Eu, Gd, and Tb polymers were performed.

About the authors

S. Petrosyants

Kurnakov Institute of General and Inorganic Chemistry

Author for correspondence.
Email: petros@igic.ras.ru
Russian Federation, Moscow

Zh. Dobrokhotova

Kurnakov Institute of General and Inorganic Chemistry

Email: petros@igic.ras.ru
Russian Federation, Moscow

A. Ilyukhin

Kurnakov Institute of General and Inorganic Chemistry

Email: petros@igic.ras.ru
Russian Federation, Moscow

A. Gavrikov

Kurnakov Institute of General and Inorganic Chemistry

Email: petros@igic.ras.ru
Russian Federation, Moscow

N. Efimov

Kurnakov Institute of General and Inorganic Chemistry

Email: petros@igic.ras.ru
Russian Federation, Moscow

V. Novotortsev

Kurnakov Institute of General and Inorganic Chemistry

Email: petros@igic.ras.ru
Russian Federation, Moscow

Supplementary files

Supplementary Files
Action
1. JATS XML

Copyright (c) 2017 Pleiades Publishing, Ltd.