Email this article Palladium acetate complexes in the gas phase
- Authors: Yakushev I.Y.1, Gekhman A.E.1, Klyagina A.P.1, Markov A.A.1, Vargaftik M.N.1, Stolyarov I.P.1, Cherkashina N.V.1, Kornev A.B.2, Moiseev I.I.1
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- The Institute of Problems of Chemical Physics
- Issue: Vol 42, No 9 (2016)
- Pages: 604-607
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213362
- DOI: https://doi.org/10.1134/S1070328416090098
- ID: 213362
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Abstract
New palladium acetate complexes, Pd2(OOCMe)4+, Pd2(OOCMe)3+, Pd2(OOCMe)2+, and Pd2(OOCMe)+ were detected in the thermal decomposition products of trans-Pd(Py)2(OOCMe)2 by mass spectrometry with direct ion source. The geometric and electronic structures of the Pd2(μ-OOCMe)4+ cation and the Pd2(OOCMe)4 molecule were established by quantum chemical calculations (DFT with the PBE1PBE hybrid exchange correlation potential in the 6-31G*/SDD basis set) and natural orbital analysis.
About the authors
I. Ya. Yakushev
Kurnakov Institute of General and Inorganic Chemistry
Email: wahr36@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 117907
A. E. Gekhman
Kurnakov Institute of General and Inorganic Chemistry
Email: wahr36@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 117907
A. P. Klyagina
Kurnakov Institute of General and Inorganic Chemistry
Email: wahr36@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 117907
A. A. Markov
Kurnakov Institute of General and Inorganic Chemistry
Email: wahr36@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 117907
M. N. Vargaftik
Kurnakov Institute of General and Inorganic Chemistry
Author for correspondence.
Email: wahr36@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 117907
I. P. Stolyarov
Kurnakov Institute of General and Inorganic Chemistry
Email: wahr36@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 117907
N. V. Cherkashina
Kurnakov Institute of General and Inorganic Chemistry
Email: wahr36@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 117907
A. B. Kornev
The Institute of Problems of Chemical Physics
Email: wahr36@gmail.com
Russian Federation, Chernogolovka
I. I. Moiseev
Kurnakov Institute of General and Inorganic Chemistry
Email: wahr36@gmail.com
Russian Federation, Leninskii pr. 31, Moscow, 117907
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