Email this article Synthesis of alkali metal bis(salicilato)borates by microwave method
- Authors: Diamant V.A.1, Pershina K.D.1,2, Trachevskii V.V.3, Kazdobin K.A.1
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Affiliations:
- Vernadsky Institute of General and Inorganic Chemistry
- Interdepartmental Branch of Electrochemical Energy
- Kurdyumov Institute of Metal Physics
- Issue: Vol 52, No 2 (2016)
- Pages: 212-216
- Section: Article
- URL: https://journals.rcsi.science/1068-3755/article/view/229665
- DOI: https://doi.org/10.3103/S1068375516020046
- ID: 229665
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Abstract
The synthesis of lithium, sodium, and potassium bis(salicilato)borates (LiBSB, NaBSB, and KBSB) is carried out by a microwave method, whose application makes it possible to shorten the synthesis duration by 8–10 times and to obtain the product yield close to the quantitative one. The product purity and the nature of impurities are determined by thermogravimetric analysis. Additionally, the structure of the compounds is proved by the IR and NMR spectroscopy. The effect of complexing of salts with amide solvents is revealed.
About the authors
V. A. Diamant
Vernadsky Institute of General and Inorganic Chemistry
Email: kazdobin@ionc.kiev.ua
Ukraine, pr. Akademika Palladina 32/34, Kyiv, 03142
K. D. Pershina
Vernadsky Institute of General and Inorganic Chemistry; Interdepartmental Branch of Electrochemical Energy
Email: kazdobin@ionc.kiev.ua
Ukraine, pr. Akademika Palladina 32/34, Kyiv, 03142; bul’v. Vernadskogo 38A, Kyiv, 03142
V. V. Trachevskii
Kurdyumov Institute of Metal Physics
Email: kazdobin@ionc.kiev.ua
Ukraine, bul’v. Vernadskogo 36, Kyiv, 03142
K. A. Kazdobin
Vernadsky Institute of General and Inorganic Chemistry
Author for correspondence.
Email: kazdobin@ionc.kiev.ua
Ukraine, pr. Akademika Palladina 32/34, Kyiv, 03142
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