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Том 60, № 3 (2017)

Coal

Determining the cause-and-effect relationships responsible for coal properties. 3. Association of chemical elements and role of indicators and accompanying elements in assessing the variability of beds’ mineral composition

Ivanov V., Isaeva E., Maerkov P.

Аннотация

In the development of productive coal and oil beds, certain geochemical conditions facilitate the formation of elementary associations that include indicator elements and accompanying elements. The determination of those associations permits the identification of the features of mineral formation in the beds and the processes that affect the variability of the mineral composition in the intervening rock.

Coke and Chemistry. 2017;60(3):91-95
pages 91-95 views

Influence of weathering on the composition and properties of coal

Semenova S., Patrakov Y.

Аннотация

The influence of coal oxidation in the bed on the structural features and basic properties of the coal is analyzed. Unoxidized and oxidized coal samples are compared.

Coke and Chemistry. 2017;60(3):96-101
pages 96-101 views

Coke

Determining the strength of coke under crushing forces

Toryanik E., Gryzlov A., Zhuravsky A., Kubrak S.

Аннотация

Despite the many characteristics of coal relating to its use as blast-furnace fuel, few characteristics have been proposed to predict the productivity of the furnace and its coke consumption. Drum tests of coke permit ample assessment of its ability to withstand mechanical loads (in particular, abrasive and impact forces). At the same time, models of coke failure in the blast furnace indicate that the crushing forces on the coke play an important role. Thanks to those forces, the mean piece size of the coke declines as it falls though the furnace. The method used to determine the coke’s ability to withstand abrasive and impact forces has been codified in GOST State Standards (in terms of the strength indices M25, M40, and M10). However, there is no standard method for assessing the ability of the coke to withstand crushing forces. To address that deficiency, a compact system for determination of the coke’s ability to withstand crushing forces is proposed: it consists of a press for the creation of compressive forces; a matrix with a punch in which the coke sample may be placed; and an instrument for measuring the compressive force (the crushing force). Values of the compressive strength determined using the new system are presented for various coke samples.

Coke and Chemistry. 2017;60(3):102-107
pages 102-107 views

Determining the air excess in the heating of coke furnaces. 3. Calculation of the air excess

Zublev D., Modakalov S., Sizov A., Barsky V., Kravchenko A.

Аннотация

The chemical mechanism by which coke-oven gas burns in the heating ducts of coke ovens is considered. A formula is obtained for the air excess. In contrast to the existing formula, the proposed version takes account of not only the content of oxygen, carbon monoxide, and carbon dioxide in the combustion products but also the content of sulfur dioxide, hydrogen, methane, nitrogen oxides. Analysis of the combustion products in the heating ducts of a coke battery with 30.9-m3 ovens shows that the content of incombustible components in the coke-oven gas may reach 3%. Calculation of the air excess by means of the proposed formula permits improvement in the uniformity of the temperature distribution in the heating system, the prevention of specific lining defects, and decrease in atmospheric emissions when the coke battery is heated by means of coke-oven gas. The proposed method of determining the air excess may be used not only in equipment for coke production but also in other metallurgical systems where coke-oven gas is burned.

Coke and Chemistry. 2017;60(3):108-112
pages 108-112 views

Equipment and Power Systems

Intensification of heat transfer in the heating ducts of coke batteries

Naletov V.

Аннотация

On the basis of a model of the gas flow in the heating duct, artificial turbulization is proposed as a means of intensifying the heat transfer in coke batteries. When using a brick lining of special form, the heat transfer in the heating duct is intensified as a result of the destruction of the laminar wall layer, with slight increase in the hydraulic drag. That improves the energy efficiency of the system.

Coke and Chemistry. 2017;60(3):113-118
pages 113-118 views

Utilization of Production Wastes

Utilizing waste tires with steel cord in coke production

Pavlovich L., Solovyova N., Strakhov V.

Аннотация

The utilization of waste tires in coking, without extraction of the steel cord, is evaluated in the laboratory. The results show that using discarded tires with steel cord improves the yield and quality of the coke produced and also the yield of valuable byproducts: benzene and coal tar.

Coke and Chemistry. 2017;60(3):119-126
pages 119-126 views

Ignition of fuel based on filter cake

Valiullin T., Vershinina K., Lyrshchikov S., Shevyrev S.

Аннотация

Coal–water slurry containing petrochemicals is of increasing interest as a fuel. In the present work, the ignition and combustion of such fuel based on spent turbine oil and mixtures of flotation waste from coal enrichment (filter cakes containing D, K, SS, and T coal) are experimentally studied. The ignition delay time, complete combustion time, and minimum ignition temperature are determined as a function of the concentration of fuel components, the oxidant temperature, and the size of the droplets held stationary in the oxidant flux at the junction of a low-inertia thermocouple. Variation in the proportions of components within the filter- cake mixture changes the ignition characteristics of the slurry (the complete combustion time and ignition delay time). The metamorphic development of the coal present in the filter cakes significantly affects the ignition and combustion of such coal–water–oil slurry.

Coke and Chemistry. 2017;60(3):127-132
pages 127-132 views

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