Sorption technology of recovery of indium from solutions of zinc production

Resumo

Sorption of indium ions from polycomponent solutions with preliminarily reduced iron(III), which contain, g/dm³, 0.084 In³⁺, 6.2 Fe²⁺, 67.0 Zn²⁺, and 19.6 H₂SO₄, on the Metosol reagent, is investigated in the dynamic mode. The Metosol reagent represents montmorillonite of composition (Na,Ca)_0.3(Al,Mg)₂Si₄O₁₀(OH)₂(H₂O)_n, modified with di(2-ethylhexyl)phosphoric acid. The absorption dynamics of ions by it is investigated by frontal chromatography. The values of working (DEC) and total (CDEC) dynamic exchange capacities of the mineral sorbent are determined depending on the eluent specific passing rate and temperature. The main parameters of the sorption technology of the selective recovery of indium from process solutions of the zinc production on the Metosol reagent in columns followed by the desorption of metal with the hydrochloric acid solution (1: 1) are substantiated and calculated.