Lead production from recycled paste of lead acid batteries with SiC-Na2CO3


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Abstract

A novel pyrometallurgical route was used to reduce the lead paste to obtain metallic lead with different additions of sodium carbonate at 850°C in a silicon carbide crucible. The process allows to obtain a high recovery of metallic lead in a single step and a slag constituted mainly by lead silicate. Products obtained were characterized by atomic absorption, X-ray powder diffraction and SEM-EDS techniques. A thermodynamic study was carried out with the software FactSage to determinate the compounds formation to the experimental conditions. High amounts of Na2CO3 and SiC promoted the formation of a lead sulfide compound which decreased the lead recovery.

About the authors

Angelica Sánchez M.

Departamento de Ingeniería Metalúrgica

Author for correspondence.
Email: ange20_80@hotmail.com
Mexico, Postal, 118431

Victor Hugo Gutiérrez P.

Ingeniería Metalúrgica, UPIIZ—Instituto Politécnico Nacional. Blvd. del Bote S/N

Email: ange20_80@hotmail.com
Mexico, Zacatecas, C.P. 98160

Alejandro Cruz R.

Departamento de Ingeniería Metalúrgica

Email: ange20_80@hotmail.com
Mexico, Postal, 118431

Ricardo Gerardo Sánchez A.

Departamento de Ingeniería Metalúrgica

Email: ange20_80@hotmail.com
Mexico, Postal, 118431

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