Email this article Reaction of (chloromethyl)trichlorosilane with 2,2-dimethylpropane-1,3-diol
- Authors: Lazareva N.F.1, Sterkhova I.V.1
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Affiliations:
- A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
- Issue: Vol 66, No 12 (2017)
- Pages: 2339-2342
- Section: Brief Communications
- URL: https://journals.rcsi.science/1066-5285/article/view/241879
- DOI: https://doi.org/10.1007/s11172-017-2026-y
- ID: 241879
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Abstract
(Chloromethyl)trichlorosilane reacts with 2,2-dimethylpropane-1,3-diol to produce α-carbofunctional heterocycles, 2-chloro-2-(chloromethyl)-5,5-dimethyl-1,3,2-dioxasilinane and 2,8-dichloro-2,8-bis(chloromethyl)-5,5,11,11-tetramethyl-1,3,7,9-tetraoxa-2,8-disilacyclododecane. The synthesized macroheterocycle is the first structurally characterized 1,3,7,9-tetraoxa-2,8-disilacyclododecane derivative.
About the authors
N. F. Lazareva
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Author for correspondence.
Email: nataly_lazareva@irioch.irk.ru
Russian Federation, 1 ul. Favorskogo, Irkutsk, 664033
I. V. Sterkhova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: nataly_lazareva@irioch.irk.ru
Russian Federation, 1 ul. Favorskogo, Irkutsk, 664033
