Synthesis and structure of the complex of uranyl citraconate with urea
- 作者: Serezhkina L.1, Novikov S.1, Grigor’ev M.2, Kolotilina M.1, Serezhkin V.1
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隶属关系:
- Samara National Research University
- Frumkin Institute of Physical Chemistry and Electrochemistry
- 期: 卷 58, 编号 5 (2016)
- 页面: 451-456
- 栏目: Article
- URL: https://journals.rcsi.science/1066-3622/article/view/223490
- DOI: https://doi.org/10.1134/S1066362216050027
- ID: 223490
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详细
Crystals of [UO2(C5H4O4)(urea)2], where C5H4O42– is citraconate ion, were prepared and studied by IR spectroscopy and single crystal X-ray diffraction. The structure of the crystals is formed by chains having the same composition as the compound as a whole and belonging to the crystal-chemical group AТ11M21 (A = UO22+, Т11 = C5H4O42–, M1 = urea) of uranyl complexes. Comparative analysis of nonvalent interactions in the structures of uranyl complexes with citraconate ions was performed by the method of molecular Voronoi–Dirichlet polyhedra.
作者简介
L. Serezhkina
Samara National Research University
编辑信件的主要联系方式.
Email: Lserezh@samsu.ru
俄罗斯联邦, ul. Akad. Pavlova 1, Samara, 443011
S. Novikov
Samara National Research University
Email: Lserezh@samsu.ru
俄罗斯联邦, ul. Akad. Pavlova 1, Samara, 443011
M. Grigor’ev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: Lserezh@samsu.ru
俄罗斯联邦, Leninskii pr. 31, korp. 4, Moscow, 119071
M. Kolotilina
Samara National Research University
Email: Lserezh@samsu.ru
俄罗斯联邦, ul. Akad. Pavlova 1, Samara, 443011
V. Serezhkin
Samara National Research University
Email: Lserezh@samsu.ru
俄罗斯联邦, ul. Akad. Pavlova 1, Samara, 443011