Thermal Stability of Nitric Acid Solutions of Hydrazine Nitrate


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Thermal stability of hydrazine nitrate (HN) in solutions in 4–12 M HNO3 in the temperature interval 70–150°C was studied. Exothermic reactions accompanied by gas evolution arise in such systems under definite conditions. The intensity of such reactions depends on the component concentrations and temperature. The characteristics of the exothermic processes were determined to evaluate the explosion safety of process operations. Because of sharp pressure buildup in apparatuses, exothermic processes in the course of evaporation of HN-containing nitric acid solutions are hazardous from the viewpoint of radiation accidents.

Sobre autores

E. Nazin

Scientific and Technical Center for Nuclear and Radiation Safety

Email: bl174@bk.ru
Rússia, ul. Malaya Krasnosel’skaya 2/8, korp. 5, Moscow, 107140

G. Zachinyaev

Scientific and Technical Center for Nuclear and Radiation Safety

Email: bl174@bk.ru
Rússia, ul. Malaya Krasnosel’skaya 2/8, korp. 5, Moscow, 107140

E. Belova

Frumkin Institute of Physical Chemistry and Electrochemistry

Autor responsável pela correspondência
Email: bl174@bk.ru
Rússia, Leninskii pr. 31, korp. 4, Moscow, 119071

A. Emel’yanov

Scientific and Technical Center for Nuclear and Radiation Safety; Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bl174@bk.ru
Rússia, ul. Malaya Krasnosel’skaya 2/8, korp. 5, Moscow, 107140; Leninskii pr. 31, korp. 4, Moscow, 119071

B. Myasoedov

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bl174@bk.ru
Rússia, Leninskii pr. 31, korp. 4, Moscow, 119071

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