Extraction of Radionuclides from Alkaline and Carbonate Media


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Аннотация

The review substantiates the desirability of developing spent nuclear fuel reprocessing technologies alternative to the Purex process. The practical use of radiochemical technologies based on alkaline and carbonate media, such as extraction of radiocesium from alkaline high-level waste and CARBEX process, is considered. Extraction of actinides with aliphatic amines, β-diketones, phenol derivatives (alkylpyrocatechols, aminomethylphenols, alkylphenol oligomers, calixarenes), and carboxylic acids, as well as extraction in two-phase aqueous systems based on water-soluble polymers, is discussed. The extraction of technetium is considered separately.

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Об авторах

I. Smirnov

Khlopin Radium Institute; Ozersk Institute of Technology, Moscow Engineering Physics Institute; St. Petersburg State University

Автор, ответственный за переписку.
Email: igor_smirnov@khlopin.ru
Россия, 2-i Murinskii pr. 28, St. Petersburg, 194021; pr. Pobedy 48, Ozersk, Chelyabinsk oblast, 456783; Universitetskaya nab. 7–9, St. Petersburg, 199034

M. Karavan

Khlopin Radium Institute; Ozersk Institute of Technology, Moscow Engineering Physics Institute; St. Petersburg State University

Email: igor_smirnov@khlopin.ru
Россия, 2-i Murinskii pr. 28, St. Petersburg, 194021; pr. Pobedy 48, Ozersk, Chelyabinsk oblast, 456783; Universitetskaya nab. 7–9, St. Petersburg, 199034

M. Logunov

Ozersk Institute of Technology, Moscow Engineering Physics Institute

Email: igor_smirnov@khlopin.ru
Россия, pr. Pobedy 48, Ozersk, Chelyabinsk oblast, 456783

I. Tananaev

Ozersk Institute of Technology, Moscow Engineering Physics Institute; Far Eastern Federal University; Frumkin Institute of Physical Chemistry and Electrochemistry

Email: igor_smirnov@khlopin.ru
Россия, pr. Pobedy 48, Ozersk, Chelyabinsk oblast, 456783; ul. Sukhanova 8, Vladivostok, 690091; Leninskii pr. 31, korp. 4, Moscow, 119071

B. Myasoedov

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: igor_smirnov@khlopin.ru
Россия, Leninskii pr. 31, korp. 4, Moscow, 119071


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