Fluorinated nucleogenic phenyl cations and nuclear-chemical route to previously unknown heterocyclic derivatives
- Авторлар: Shchepina N.1, Avrorin V.2, Badun G.3, Ukhanov S.4
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Мекемелер:
- Natural Science Institute
- St. Petersburg State University
- Moscow State University
- Perm National Research Polytechnic University
- Шығарылым: Том 58, № 1 (2016)
- Беттер: 92-94
- Бөлім: Article
- URL: https://journals.rcsi.science/1066-3622/article/view/223338
- DOI: https://doi.org/10.1134/S1066362216010148
- ID: 223338
Дәйексөз келтіру
Аннотация
A new reactive species, fluorinated phenyl cation generated by β-decay of tritium in difluoroditritiobenzene, was used for introducing fluorinated phenyl fragment into organic compounds. Studies of ion–molecule reactions have shown that, similarly to the unsubstituted nucleogenic phenyl cation, p-difluorophenyl cation directly phenylates the N atom in the heterocyclic ring of quinoline. The nuclear-chemical method allows not only generation of nucleogenic species of various structures, but also one-step synthesis of previously unknown and difficultly accessible heterocyclic derivatives labeled with tritium.
Авторлар туралы
N. Shchepina
Natural Science Institute
Хат алмасуға жауапты Автор.
Email: neshchepina@mail.ru
Ресей, ul. Genkelya 4, Perm, 614990
V. Avrorin
St. Petersburg State University
Email: neshchepina@mail.ru
Ресей, Universitetskaya nab. 7/9, St. Petersburg, 199034
G. Badun
Moscow State University
Email: neshchepina@mail.ru
Ресей, Moscow, 119991
S. Ukhanov
Perm National Research Polytechnic University
Email: neshchepina@mail.ru
Ресей, Komsomol’skii pr. 29, Perm, 614990