Photoinduced conversion of carbon dioxide and water molecules to methanol on the surface of molybdenum oxide MoO  x   ( x  &lt; 2)

I. V. Silaev; S. A. Khubezhov; A. G. Ramonova; G. S. Grigorkina; A. G. Kaloeva; Z. S. Demeev; A. P. Bliev; D. Sekiba; S. Ogura; K. Fukutani; T. T. Magkoev

doi:10.1134/S1063785016030147

Photoinduced conversion of carbon dioxide and water molecules to methanol on the surface of molybdenum oxide MoO_x (x < 2)

Авторы: Silaev I.V.¹, Khubezhov S.A.¹, Ramonova A.G.¹, Grigorkina G.S.¹, Kaloeva A.G.¹, Demeev Z.S.¹, Bliev A.P.¹, Sekiba D.², Ogura S.², Fukutani K.², Magkoev T.T.¹
Учреждения:
1. Khetagurov North Ossetian State University
2. University of Tokyo
Выпуск: Том 42, № 3 (2016)
Страницы: 271-273
Раздел: Article
URL: https://journals.rcsi.science/1063-7850/article/view/197816
DOI: https://doi.org/10.1134/S1063785016030147
ID: 197816

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X-ray and UV photoelectron spectroscopic data are used to demonstrate that, when pulsed laser light with a photon energy of 6.4 eV acts on the surface of nonstoichiometric molybdenum oxide MoO_x (x < 2), methanol is effectively formed from adsorbed molecules of carbon dioxide and water. The processes in which CO₂ and H₂O molecules are adsorbed on substrate surface defects and their bonds are activated, enhanced under the effect of photons, should be regarded as the key factors.