Formation of nanodiamond films from aqueous suspensions during spin coating


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The formation of multifunctional ordered arrays of detonation diamond particles is studied during self-assembling in spin coating of films of evaporating microdroplets. It is shown that the most homogeneous layer of diamond particles on a crystalline silicon substrate forms at a rate of substrate rotation of 8000 min–1, whereas a relation between the distribution of particles and the radius is clearly detected at rates of about 2000 min–1. As the rate of substrate rotation increases from 2500 to 8000 min–1, the density of the coating of a silicon substrate with diamond nanoparticles decreases approximately threefold. A model is proposed to estimate the increase in the number of individual diamond “points” with the substrate rotation frequency.

作者简介

P. Lebedev-Stepanov

Center of Photochemistry; National Research Nuclear University MEPhI

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Email: petrls@mail.ru
俄罗斯联邦, Moscow, 119421; Kashirskoe sh. 31, Moscow, 115421

S. Molchanov

Center of Photochemistry

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俄罗斯联邦, Moscow, 119421

A. Vasil’ev

National Research Centre Kurchatov Institute

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俄罗斯联邦, pl. Kurchatova 1, Moscow, 123182

V. Mitrokhin

Center of Photochemistry

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俄罗斯联邦, Moscow, 119421

G. Yurasik

Center of Photochemistry

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俄罗斯联邦, Moscow, 119421

A. Aleksenskii

Ioffe Physical Technical Institute

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俄罗斯联邦, Politekhnicheskaya ul. 26, St. Petersburg, 194021

A. Dideikin

Ioffe Physical Technical Institute

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俄罗斯联邦, Politekhnicheskaya ul. 26, St. Petersburg, 194021


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