Production of Complex Hydrosulphates in the K3H(SO4)2–Rb3H(SO4)2 Series: Part I


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The phase equilibria in the K3H(SO4)2–Rb3H(SO4)2–H2O cross section have been investigated under isothermal conditions at 25°C. The concentration limits of crystallization of solid solutions with the general formulas (Rb1 – xKx)3H(SO4)2 and (Rb1 – xKx)2SO4 are determined. The dependences of the equilibria of saturated solution on the initial production conditions are revealed. The growth conditions for large single crystals of complex acid rubidium–potassium sulfates are determined.

作者简介

V. Komornikov

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Russian Academy of Sciences

编辑信件的主要联系方式.
Email: v.a.kom@mail.ru
俄罗斯联邦, Moscow, 119333

V. Grebenev

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Russian Academy of Sciences

Email: v.a.kom@mail.ru
俄罗斯联邦, Moscow, 119333

I. Timakov

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Russian Academy of Sciences

Email: v.a.kom@mail.ru
俄罗斯联邦, Moscow, 119333

D. Ksenofontov

Moscow State University

Email: v.a.kom@mail.ru
俄罗斯联邦, Moscow

P. Andreev

Lobachevsky State University of Nizhny Novgorod

Email: v.a.kom@mail.ru
俄罗斯联邦, Nizhny Novgorod, 603950

I. Makarova

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Russian Academy of Sciences

Email: v.a.kom@mail.ru
俄罗斯联邦, Moscow, 119333

E. Selezneva

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Russian Academy of Sciences

Email: v.a.kom@mail.ru
俄罗斯联邦, Moscow, 119333

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