X-Ray Study of 7a-(2-Chlorophenyl)-7a,8a,9,10,11,12ahexadronaptho[ 1',2':4,5]furo[3,2-d]pyrrolo[2,1-b]oxazole and 2-(4-fluorophenyl)-2-hydroxynaptho[2,1-b]furan-1(2H)-one
- 作者: Kumar B.1, Battini N.2,3, Ahmed Q.2,3, Ali A.2,4, Gupta V.1
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隶属关系:
- X-ray Crystallography Laboratory, Post-Graduate Department of Physics and Electronics
- Medicinal Chemistry Division
- Academy of Scientific and Innovative Research (AcSIR)
- Natural Product Chemistry Division
- 期: 卷 63, 编号 3 (2018)
- 页面: 382-387
- 栏目: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/192464
- DOI: https://doi.org/10.1134/S1063774518030045
- ID: 192464
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详细
Two organic compounds, namely, 7a-(2-chlorophenyl)-7a,8a,9,10,11,12a-hexadronaptho-[1',2':4,5]furo[3,2-d]pyrrolo[2,1-b]oxazole (I) and 2-(4-fluorophenyl)-2-hydroxynaptho[2,1-b]furan- 1(2H)-one (II), were synthesised via microwave reaction using commercially available glyoxal monohydrate, β-Naphthol, pyrrolidine, and Cu(OAc)2 · H2O, and their crystal structures were determined by X-ray diffraction technique. The crystals of compound I are orthorhombic, sp. gr. P212121, a = 6.8750(5) Å, b = 8.2248(9) Å, c = 31.720(3) Å, and Z = 4, while the crystals of compound II are monoclinic, sp. gr. P21/c, a = 7.4038(9) Å, b = 18.592(2) Å, c = 10.4589(12) Å, β = 107.492(13)°, and Z = 4. The inter molecular O–H···O, C–H···O, and C–H···F hydrogen interactions play significant role in stabilizing the crystal structure in the compound II. In addition, aromatic π–π interactions are also observed in the structure of the compound II.
作者简介
Balbir Kumar
X-ray Crystallography Laboratory, Post-Graduate Department of Physics and Electronics
Email: vivek_gupta2k2@hotmail.com
印度, Jammu Tawi, 180006
Narsaiah Battini
Medicinal Chemistry Division; Academy of Scientific and Innovative Research (AcSIR)
Email: vivek_gupta2k2@hotmail.com
印度, Jammu, 180001; 2-Rafi Marg, New Delhi
Qazi Ahmed
Medicinal Chemistry Division; Academy of Scientific and Innovative Research (AcSIR)
Email: vivek_gupta2k2@hotmail.com
印度, Jammu, 180001; 2-Rafi Marg, New Delhi
Asif Ali
Medicinal Chemistry Division; Natural Product Chemistry Division
Email: vivek_gupta2k2@hotmail.com
印度, Jammu, 180001; Canal Road, Jammu, 180001
Vivek Gupta
X-ray Crystallography Laboratory, Post-Graduate Department of Physics and Electronics
编辑信件的主要联系方式.
Email: vivek_gupta2k2@hotmail.com
印度, Jammu Tawi, 180006