Study of the K2Ni(SO4)2 ∙ 6H2O–K2Co(SO4)2 ∙ 6H2O–H2O diagram and determination of the conditions for growing K2(Ni,Co)(SO4)2 ∙ 6H2O mixed crystals
- 作者: Zhokhov A.A.1, Masalov V.M.1, Zverkova I.I.1, Emelchenko G.A.1, Manomenova V.L.2, Rudneva E.B.2, Vasilieva N.A.2, Voloshin A.E.2
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隶属关系:
- Institute of Solid State Physics
- Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
- 期: 卷 61, 编号 6 (2016)
- 页面: 1027-1030
- 栏目: Crystal Growth
- URL: https://journals.rcsi.science/1063-7745/article/view/190444
- DOI: https://doi.org/10.1134/S1063774516060195
- ID: 190444
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详细
The phase diagram of the K2Ni(SO4)2 · 6H2O–K2Co(SO4)2 · 6H2O–H2O ternary system is investigated in the temperature range of 30–70°С, and a relationship between the compositions of the equilibrium phases of the K2CoxNi(1–x)(SO4)2 · 6H2O (KCNSH) solid solution and the growth solution is established. It is shown how the salt compositions of the liquid and solid phases change during crystal growth upon slow cooling of solution. A dependence of the lattice parameters of the KCNSH solid solution on the concentration of isomorphic components is experimentally found.
作者简介
A. Zhokhov
Institute of Solid State Physics
Email: emelch@issp.ac.ru
俄罗斯联邦, Chernogolovka, 142432
V. Masalov
Institute of Solid State Physics
Email: emelch@issp.ac.ru
俄罗斯联邦, Chernogolovka, 142432
I. Zverkova
Institute of Solid State Physics
Email: emelch@issp.ac.ru
俄罗斯联邦, Chernogolovka, 142432
G. Emelchenko
Institute of Solid State Physics
编辑信件的主要联系方式.
Email: emelch@issp.ac.ru
俄罗斯联邦, Chernogolovka, 142432
V. Manomenova
Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Email: emelch@issp.ac.ru
俄罗斯联邦, Moscow, 119333
E. Rudneva
Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Email: emelch@issp.ac.ru
俄罗斯联邦, Moscow, 119333
N. Vasilieva
Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Email: emelch@issp.ac.ru
俄罗斯联邦, Moscow, 119333
A. Voloshin
Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”
Email: emelch@issp.ac.ru
俄罗斯联邦, Moscow, 119333
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