Synthesis and Structural Characterization of a Cobalt Coordination Polymer with Formate and Bis(4-(1H-imidazol-1-yl)phenyl)methanone Ligands


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A cobalt coordination polymer, {[Co(L1)2(H2O)2] · (HCOO)2 · H2O}n, where L1 is a bis(4-(1H-imidazol-1-yl)phenyl)methanone, has been synthesized and characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. The crystal crystallizes in the triclinic sp. gr. \(P\bar {1}\) with the unit cell parameters a = 7.9504(6), b = 10.0231(7), c = 13.3129(8) Å, and α = 88.399(5)°, β = 75.310(6)°, γ = 79.179(6)°, Z = 1. The Co2+ ion has a distorted octahedral environment with two O atoms from two water molecules and four N atoms from four L1 ligands. A thermal stability of polymer has been discussed.

作者简介

Shu-Wen Sun

Department of Applied Chemistry, Yuncheng University

Email: wgf1979@126.com
中国, Yuncheng, 044000

Li-Xin Meng

Department of Applied Chemistry, Yuncheng University

编辑信件的主要联系方式.
Email: meng.lixin@126.com
中国, Yuncheng, 044000

Gao-Feng Wang

Department of Applied Chemistry, Yuncheng University

编辑信件的主要联系方式.
Email: wgf1979@126.com
中国, Yuncheng, 044000

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