Molecular and Crystal Structure of 2-{(E)-[(5-Chloro-2-methoxyphenyl)imino]methyl}-4-nitrophenol


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The molecular structure of the title compound, C14H11ClN2O4, was determined by single crystal X-ray diffraction. The compound crystallizes in the monoclinic sp. gr. P21/c with Z = 4. The title compound, C14H11ClN2O4, is a Schiff base which adopts the phenol-imine tautomeric form in the solid state.The molecule is almost planar and the dihedral angle between the planes of two aromatic ring is 2.2(1)°. The molecular structure is stabilized by intramolecular O–H···N hydrogen bond which generates a six-membered ring. In the crystal structure, the molecules are linked together by intermolecular C–H···O interactions.

Sobre autores

Nihal Kaynar

Department of Physics, Faculty of Arts and Sciences

Autor responsável pela correspondência
Email: nihal_kan84@windowslive.com
Turquia, Amasya, 05100

Erbil Ağar

Department of Chemistry, Faculty of Arts and Sciences

Email: nihal_kan84@windowslive.com
Turquia, Samsun, 55139

Hasan Tanak

Department of Chemistry, Faculty of Arts and Sciences

Email: nihal_kan84@windowslive.com
Turquia, Samsun, 55139

Songul Sahin

Department of Chemistry, Faculty of Arts and Sciences

Email: nihal_kan84@windowslive.com
Turquia, Samsun, 55139

Orhan Büyükgüngör

Department of Physics, Faculty of Arts and Sciences

Email: nihal_kan84@windowslive.com
Turquia, Samsun, 55139

Metin Yavuz

Department of Physics, Faculty of Arts and Sciences

Email: nihal_kan84@windowslive.com
Turquia, Samsun, 55139

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