Crystal structure of (E)-3-fluoro-N-((5-nitrothiophen-2-yl)methylene)aniline


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Abstract

The structure of the title compound C11H7FN2O2S was characterized by single crystal X-ray diffraction. The compound crystallizes in the monoclinic space group P21/n with Z = 12, i.e. with three molecules in asymmetric unit. The molecules are not planar: the dihedral angles between the planes of thiophene and the benzene rings are 42.3(3)°, 42.0(3)°, and 48.9(2)°. In the crystal, intermolecular C–H···F interactions link the molecules through R22 (14) ring motif. The crystal packing is also stabilized by π···π interactions.

About the authors

Şadiye Karataş

Department of Physics, Faculty of Arts and Sciences

Email: hasantanak@gmail.com
Turkey, Amasya, 05100

Hasan Tanak

Department of Physics, Faculty of Arts and Sciences

Author for correspondence.
Email: hasantanak@gmail.com
Turkey, Amasya, 05100

Ayşen Alaman Ağar

Department of Chemistry, Faculty of Arts and Sciences

Email: hasantanak@gmail.com
Turkey, Samsun

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