Email this article Synthesis, Crystal Structure, and Luminescent Properties of Ag(I) Coordination Polymer with Tricarboxylic Acid and Flexible N-donor Ligand
- Authors: Lu J.F.1, Xu Y.H.1, Li P.A.1, Jin L.X.1, Zhao C.B.1, Guoand X.H.1, Ge H.G.1
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Affiliations:
- Key Laboratory of Catalysis, College of Chemical and Environment Science
- Issue: Vol 62, No 7 (2017)
- Pages: 1046-1050
- Section: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/191627
- DOI: https://doi.org/10.1134/S1063774517070173
- ID: 191627
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Abstract
The reaction of AgNO3 with combinations of 1,3-bis(4-pyridyl)propane (bpp) and 1,3,5-benzenetricarboxylic acid (H3btc) in aqueous alcohol/ammonia at room temperature produces crystals of {[Ag6(H2O)2(bpp)6] · (btc)2 · 25H2O}n (Ι). Single crystal X-ray diffraction analysis reveals that the complex Ι consists of 1D infinite cationic chains of [Ag(bpp)]nn+ and [Ag(H2O)(bpp)]nn+ which are further linked into the cation layer of [Ag(bpp)]nn+ by Ag···π interactions. The noncoordinated btc3− serves as template driving surrounding water molecules to aggregate into the anionic water layer. The neighboring anionic water layer and cationic layer were further alternately joined into a 3D sandwich-like framework by hydrogen bonding. In addition, the luminescent properties of Ι were investigated.
About the authors
J. F. Lu
Key Laboratory of Catalysis, College of Chemical and Environment Science
Author for correspondence.
Email: jiufulu@163.com
China, Hanzhong
Y. H. Xu
Key Laboratory of Catalysis, College of Chemical and Environment Science
Email: gehg@snut.edu.cn
China, Hanzhong
P. A. Li
Key Laboratory of Catalysis, College of Chemical and Environment Science
Email: gehg@snut.edu.cn
China, Hanzhong
L. X. Jin
Key Laboratory of Catalysis, College of Chemical and Environment Science
Email: gehg@snut.edu.cn
China, Hanzhong
C. B. Zhao
Key Laboratory of Catalysis, College of Chemical and Environment Science
Email: gehg@snut.edu.cn
China, Hanzhong
X. H. Guoand
Key Laboratory of Catalysis, College of Chemical and Environment Science
Email: gehg@snut.edu.cn
China, Hanzhong
H. G. Ge
Key Laboratory of Catalysis, College of Chemical and Environment Science
Author for correspondence.
Email: gehg@snut.edu.cn
China, Hanzhong
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