Studies of the CO oxidation kinetic regularities on Cu–Co–Fe oxide catalysts, bulk and deposited on the carbon nanotubes
- Authors: Ishchenko E.V.1, Gaidai C.V.1, Zakharova T.M.1, Yatsimirskii A.V.1, Shevchuk Y.S.1
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Affiliations:
- Shevchenko Kiev National University
- Issue: Vol 38, No 3 (2016)
- Pages: 169-175
- Section: Production, Structure, Properties
- URL: https://journals.rcsi.science/1063-4576/article/view/185554
- DOI: https://doi.org/10.3103/S1063457616030035
- ID: 185554
Cite item
Abstract
The effect of catalysts of the carbon nanotubes synthesis and of the technology of a Cu–Co–Fe active oxide mass deposition on the kinetic regularities of the CO oxidation reaction has been studied. It has been shown that the experimental data on both catalysts, bulk Cu–Co–Fe and deposited onto carbon nanotubes, agree with the Eley–Readil kinetic scheme. Based on the suggested mechanism, the effective reaction rate constants have been calculated by various methods. It has been shown that the use of Cu–Co–Fe catalysts deposited on carbon nanotubes offers considerable promise.
Keywords
About the authors
E. V. Ishchenko
Shevchenko Kiev National University
Author for correspondence.
Email: isch@voliacable.com
Ukraine, vul. Volodymyrs’ka 64, Kiev, 01601
C. V. Gaidai
Shevchenko Kiev National University
Email: isch@voliacable.com
Ukraine, vul. Volodymyrs’ka 64, Kiev, 01601
T. M. Zakharova
Shevchenko Kiev National University
Email: isch@voliacable.com
Ukraine, vul. Volodymyrs’ka 64, Kiev, 01601
A. V. Yatsimirskii
Shevchenko Kiev National University
Email: isch@voliacable.com
Ukraine, vul. Volodymyrs’ka 64, Kiev, 01601
Ya. S. Shevchuk
Shevchenko Kiev National University
Email: isch@voliacable.com
Ukraine, vul. Volodymyrs’ka 64, Kiev, 01601
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