Nitrogen Hemioxide: Properties and Neutralization Methods

详细

The physical and chemical properties of N₂O and methods for its trapping and decomposition are examined. It is found that organic solvents, water, hydrazine hydrate, and a solution of potassium bichromate in sulfuric acid dissolve N₂O but its stabilization by this method is unreliable. Catalytic decomposition upon heating is acknowledged to be an effective method of neutralizing N₂O. Different composite materials, including those containing d and ƒ elements, were studied as catalysts. It was found that suitable composites for catalytic decomposition of N₂O are SiO₂–Cu, Al₂O₃–Ni at 150°C and Al₂O₃–Cu, Al₂O₃–Fe, Al₂O₃–Ni, and SiO₂–Cu at 250°C. It was shown that the passage of ethanol vapors above the composites at the indicated temperature increases the degree of decomposition of N₂O by a factor of 10. The results obtained were used to develop a gas-purification system in the technology for reprocessing spent nitride fuel.