The dielectric properties and flow of electrorheological fluids based on polymer-coated nanodispersed barium tetraacetate titanyl particles upon a dynamic shear in electric fields

详细

The shear stress in flowing electrorheological fluids consisting of PMS-20 poly(dimethylsiloxane) filled with nanodispersed barium tetraacetate titanyl particles coated with polymers (polyethyleneimine, poly(ethylene glycol), and polyethyloxazoline) has been studied as depending on the strengths of direct- and alternating-current (f = 50 Hz) electric fields. Results of analyzing the dielectric spectra of electrorheological fluids in a frequency range of 25–10⁶ Hz have been presented. The values of the shear stress in the flowing fluids as depending on the nature of a polymer adsorbed on the particle surface decrease in a series corresponding to a reduction in the Maxwell–Wagner relaxation times of the suspensions. The current-voltage characteristics of the electrorheological fluids at high voltages (up to 5 kV) indicate the realization of the mechanism of currents limited by the space charge. The influence of an adsorbed polymer on the magnitude of the electrorheological effect is reduced to blocking polar groups on the particle surface and variations in the conductivity, effective dielectric permittivity, and loss tangents of filler materials. An increase in the contribution from these factors leads to a gradual decrease in the magnitude of the electrorheological effect.