Features of the Interaction between Dodecyltrimethylammonium Bromide Micelles and Sodium 4-Styrene Sulfonate


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Spin probe EPR spectroscopy and UV spectroscopy have been employed to study the interaction between a hydrophobic anionic monomer, sodium styrene sulfonate, and micelles of a cationic surfactant, dodecyltrimethylammonium bromide. It has been shown that the interaction with the monomer decreases the critical micelle concentration of the surfactant in aqueous solutions. It has been found that the monomer is incorporated into micelles; therefore, the presence of the surfactant may hinder polymerization of the monomer.

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Yu. Shulevich

Volgograd State Technical University

编辑信件的主要联系方式.
Email: shulevich@vstu.ru
俄罗斯联邦, Volgograd, 400005

Yu. Zakharova

Department of Chemistry, Moscow State University

Email: shulevich@vstu.ru
俄罗斯联邦, Moscow, 119992

M. Motyakin

Semenov Institute of Chemical Physics, Russian Academy of Sciences

Email: shulevich@vstu.ru
俄罗斯联邦, Moscow, 119991

I. Ionova

Semenov Institute of Chemical Physics, Russian Academy of Sciences

Email: shulevich@vstu.ru
俄罗斯联邦, Moscow, 119991

E. Dukhanina

Volgograd State Technical University

Email: shulevich@vstu.ru
俄罗斯联邦, Volgograd, 400005

A. Navrotskii

Volgograd State Technical University

Email: shulevich@vstu.ru
俄罗斯联邦, Volgograd, 400005

I. Novakov

Volgograd State Technical University

Email: shulevich@vstu.ru
俄罗斯联邦, Volgograd, 400005

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