Specific Features of Ion Transport in New Nanocomposite Gel Electrolytes Based on Cross-Linked Polymers and Silica Nanoparicles

Resumo

The spesific features of ion transport are studied in the nanocomposite system based on a network matrix synthesized by radical polymerization of polyethylene glycol diacrylate in the presence of liquid aprotic electrolyte containing 1 M LiBF₄ in γ-butyrolactone and SiO₂ nanopowder. The self-diffusion coefficients measured by ⁷Li NMR spectroscopy with pulsed field gradient have a maximum at 2 wt % SiO₂ nanoparticles. Nanocomposites of the latter composition exhibit the highest cation transport numbers (0.49) and the maximum of conductivity in the temperature interval under study (from –70 to 100°С): 4 mS/cm at 20°С and 1 mS/cm at –70°С. The second conductivity maximum at 6 wt % is characterized merely by the low effective activation energy of conduction. Possible mechanisms are invoked to explain the increase in conductivity. The first mechanism is based on the increase in the number of mobile charge carriers which may be a result of salt dissociation to ions, the second mechanism is associated with the development of a large number of favorable pathways for ion transport.