电邮这篇文章 Comparative study of the ion conductivities of substituted tetrabutylammonium salts (C4H9)4N]BF4 and [(C4H9)4N]Br
- 作者: Iskakova A.1, Ulikhin A.1, Uvarov N.1,2,3, Gerasimov K.1, Mateishina Y.1
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隶属关系:
- Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch
- Novosibirsk State Technical University
- Novosibirsk State University
- 期: 卷 53, 编号 8 (2017)
- 页面: 880-883
- 栏目: Article
- URL: https://journals.rcsi.science/1023-1935/article/view/189006
- DOI: https://doi.org/10.1134/S1023193517080079
- ID: 189006
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详细
The ion conductivity of the salts [(C4H9)4N]BF4 and [(C4H9)4N]Br was studied in vacuum at temperatures from room temperature to 190 and 135°C, respectively. The salts have phase transitions to disordered high-temperature phases accompanied by an increase in conductivity. [(C4H9)4N]Br has higher conductivity than [(C4H9)4N]BF4. As the conductivity decreases with the increasing size of the anion, the BF4– and Br– anions are the most probable current carriers in the salts.
作者简介
A. Iskakova
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch
编辑信件的主要联系方式.
Email: anastasiya.shev@gmail.com
俄罗斯联邦, Novosibirsk, 630128
A. Ulikhin
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch
Email: anastasiya.shev@gmail.com
俄罗斯联邦, Novosibirsk, 630128
N. Uvarov
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch; Novosibirsk State Technical University; Novosibirsk State University
Email: anastasiya.shev@gmail.com
俄罗斯联邦, Novosibirsk, 630128; Novosibirsk, 630073; Novosibirsk, 630090
K. Gerasimov
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch
Email: anastasiya.shev@gmail.com
俄罗斯联邦, Novosibirsk, 630128
Yu. Mateishina
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch
Email: anastasiya.shev@gmail.com
俄罗斯联邦, Novosibirsk, 630128
