Thermodynamic study of Ag8GeSe6 by EMF with an Ag4RbI5 solid electrolyte
- 作者: Alverdiev I.1, Bagkheri S.2, Imamalieva S.2, Yusibov Y.1, Babanly M.2
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隶属关系:
- Ganja State University
- Institute of Catalysis and Inorganic Chemistry
- 期: 卷 53, 编号 5 (2017)
- 页面: 551-554
- 栏目: Short Communications
- URL: https://journals.rcsi.science/1023-1935/article/view/188737
- DOI: https://doi.org/10.1134/S1023193517050032
- ID: 188737
如何引用文章
详细
The Ag–Ge–Se system was studied in the range of compositions Ag2Se–GeSe2–Se by measuring the EMF of the concentration (relative to the silver electrode) circuits with a solid electrolyte Ag4RbI5 in the temperature range 290–430 K. The polymorphic transition temperature of Ag8GeSe6 (320 K) was determined and the partial molar functions of silver were calculated for both crystal modifications of this compound based on the EMF measurements. The thermodynamic functions of formation and entropy of both modifications of Ag8GeSe6 and the thermodynamic functions of its polymorphic transition were calculated.
作者简介
I. Alverdiev
Ganja State University
Email: Babanly_mb@rambler.ru
阿塞拜疆, Ganja
S. Bagkheri
Institute of Catalysis and Inorganic Chemistry
Email: Babanly_mb@rambler.ru
阿塞拜疆, Baku
S. Imamalieva
Institute of Catalysis and Inorganic Chemistry
Email: Babanly_mb@rambler.ru
阿塞拜疆, Baku
Yu. Yusibov
Ganja State University
Email: Babanly_mb@rambler.ru
阿塞拜疆, Ganja
M. Babanly
Institute of Catalysis and Inorganic Chemistry
编辑信件的主要联系方式.
Email: Babanly_mb@rambler.ru
阿塞拜疆, Baku