Highly active and stable catalysts based on nanotubes and modified platinum for fuel cells


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Results on the development of new cathodic catalysts (monoplatinum and cobalt-modified platinum) applied on carbon nanotubes are shown. By means of a complex of electrochemical and structural techniques, it is shown that as regards their activity under model conditions and within membrane-electrode assembles, the catalysts synthesized by the polyol method are close to commercial monoplatinum systems with the same mass content of platinum (20 wt %) and their corrosion stability is double that of commercial catalysts. Platinum modified with cobalt is characterized by still higher stability, which allows considering these catalytic systems as the candidates to be used in fuel cells after the corresponding optimization.

作者简介

V. Bogdanovskaya

Frumkin Institute of Physical Chemistry and Electrochemistry

编辑信件的主要联系方式.
Email: bogd@elchem.ac.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991

E. Kol’tsova

Mendeleev University of Chemical Technology

Email: bogd@elchem.ac.ru
俄罗斯联邦, Miusskaya pl. 9, Moscow, 125047

M. Tarasevich

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bogd@elchem.ac.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991

M. Radina

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bogd@elchem.ac.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991

G. Zhutaeva

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bogd@elchem.ac.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991

A. Kuzov

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bogd@elchem.ac.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991

N. Gavrilova

Mendeleev University of Chemical Technology

Email: bogd@elchem.ac.ru
俄罗斯联邦, Miusskaya pl. 9, Moscow, 125047

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