Effect of acceptor substitution in perovskites La1–xAxMnO3 ± δ (A = Ca, Sr, Ba) on the kinetics of interaction of gas-phase oxygen
- 作者: Porotnikova N.1, Ananyev M.1,2, Eremin V.1, Molchanova N.1, Kurumchin E.1
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隶属关系:
- Institute of High-Temperature Electrochemistry, Ural Branch
- Ural Federal University named after the first President of Russia B.N. Yeltsin
- 期: 卷 52, 编号 8 (2016)
- 页面: 717-722
- 栏目: Article
- URL: https://journals.rcsi.science/1023-1935/article/view/188061
- DOI: https://doi.org/10.1134/S1023193516080103
- ID: 188061
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详细
The kinetics of interaction of gas-phase oxygen with oxygen of perovskite-like manganites La1 - xAxMnO3 ± δ (A = Ca, Sr, Ba) at a temperature of 850°C and an oxygen pressure of 1 kPa was studied by isotope exchange of oxygen with analysis of the gas phase. The rates of the interphase exchange, dissociative adsorption, and incorporation of oxygen in the crystal lattice of perovskites La0.7A0.3MnO3 ± δ (A = Ca, Sr, Ba) and La1–xSrxMnO3 ± δ (x = 0, 0.3, 0.4) were calculated. The dissociative adsorption of oxygen was found to be the limiting stage of the exchange. The influence of the defective structure of oxide La1 - xAxMnO3 ± δ on the mechanism of exchange with oxygen of the gas phase was discussed.
作者简介
N. Porotnikova
Institute of High-Temperature Electrochemistry, Ural Branch
编辑信件的主要联系方式.
Email: n.porotnikova@mail.ru
俄罗斯联邦, ul. Akademicheskaya 20, Yekaterinburg
M. Ananyev
Institute of High-Temperature Electrochemistry, Ural Branch; Ural Federal University named after the first President of Russia B.N. Yeltsin
Email: n.porotnikova@mail.ru
俄罗斯联邦, ul. Akademicheskaya 20, Yekaterinburg; ul. Mira 19, Yekaterinburg
V. Eremin
Institute of High-Temperature Electrochemistry, Ural Branch
Email: n.porotnikova@mail.ru
俄罗斯联邦, ul. Akademicheskaya 20, Yekaterinburg
N. Molchanova
Institute of High-Temperature Electrochemistry, Ural Branch
Email: n.porotnikova@mail.ru
俄罗斯联邦, ul. Akademicheskaya 20, Yekaterinburg
E. Kurumchin
Institute of High-Temperature Electrochemistry, Ural Branch
Email: n.porotnikova@mail.ru
俄罗斯联邦, ul. Akademicheskaya 20, Yekaterinburg