Electrochemical Corrosion Behavior of Monel Alloy in Carbonate Melts

Resumo

The interaction of the monel alloy and its corrosion resistance in a melt of alkali metal carbonates in an oxidizing atmosphere was studied. The selectivity of alloy dissolution and modification of the electrode surface after storage at a constant anode potential were analyzed. The generation and development of local corrosion defects (pit corrosion, intercrystallite corrosion, corrosion cracking) on monel alloy (70% nickel, 28% copper), copper, and nickel electrodes in the molten eutectic of lithium, sodium, and potassium carbonates at a working temperature of 773 K were studied. The anode polarization was accompanied by a change in the state of the electrode surface.