Single SOFC with Supporting Ni-YSZ Anode, Bilayer YSZ/GDC Film Electrolyte, and La2NiO4 + δ Cathode

Resumo

Characteristics of fuel cells with supporting Ni-YSZ anode, bilayer YSZ/GDC electrolyte with the thickness of 10 μm, and La₂NiO_{4 + δ} cathode are studied. It is shown that when humid (3% water) hydrogen is supplied to the anode and air is supplied to the cathode, the maximum values of cell’s power density are 1.05 and 0.75 W/cm² at 900 and 800°С, respectively. After the introduction of praseodymium oxide and ceria into the cathode and the anode, respectively, the power density is ca. 1 W/cm² at 700°С. It is found that the power density of a cell with impregnated electrodes weakly increases with the increase in temperature to ca. 1.4 W/cm² at 900°С. The analysis of impedance spectra by the distribution of relaxation times shows that such behavior is associated with the gas-diffusion resistance of the SOFC anode. The latter is explained by the low porosity of the anode and the high rate of fuel consumption.